{"id":{"repo_id":"wichita-thes","oai_identifier":"oai:null:10057/24967"},"canonical_url":"https://search.dev.ndltd.org/etd/wichita-thes/oai:null:10057/24967","repository":{"repo_id":"wichita-thes","name":"Wichita State University","base_url":"https://soar.wichita.edu/oai/request"},"display":{"title":"Synthesis and characterization of polymer nanocomposite materials for advanced application","abstract":"This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements.","abstract_html":"This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements.","abstract_has_math":false,"creators":["Abdelgawad, Ammar M."],"institution":"Wichita State University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Pugh, Coleen"],"committee_chairs":[],"committee_members":[],"year":2022,"date_issued":"2022-12","date_published":"2022-12","updated_at":"2026-08-21T16:50:55Z","subjects":[],"languages":["en_US"],"rights":["© Copyright 2022 by Ammar Mohamed Abdelghafar Abdelgawad All Rights Reserved"],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["d22020s"],"render_values":[{"text":"d22020s","href":null,"code":true}]}]},"links":{"outbound_url":"https://soar.wichita.edu/handle/10057/24967","outbound_label":"Repository record","outbound_source":"dc:identifier.uri"},"source_record":{"url":"https://soar.wichita.edu/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Anull%3A10057%2F24967","prefix":"dim"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Pugh, Coleen"]},{"key":"dc:creator","label":"Author","values":["Abdelgawad, Ammar M."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2023-01-26T15:13:08Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2023-01-26T15:13:08Z"]},{"key":"dc:date.issued","label":"Date","values":["2022-12"]},{"key":"dc:publisher","label":"Institution","values":["Wichita State University"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_US"]},{"key":"dc:rights","label":"Dc Rights","values":["© Copyright 2022 by Ammar Mohamed Abdelghafar Abdelgawad All Rights Reserved"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["d22020s"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://soar.wichita.edu/handle/10057/24967"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Thesis (Ph.D.)-- Wichita State University, College of Liberal Arts and Sciences, Department of Chemistry and Biochemistry"]},{"key":"dc:description.abstract","label":"Abstract","values":["This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements."]},{"key":"dc:title","label":"Title","values":["Synthesis and characterization of polymer nanocomposite materials for advanced application"]}]}],"canonical_facts":{"dc:contributor.advisor":["Pugh, Coleen"],"dc:creator":["Abdelgawad, Ammar M."],"dc:date.accessioned":["2023-01-26T15:13:08Z"],"dc:date.available":["2023-01-26T15:13:08Z"],"dc:date.issued":["2022-12"],"dc:description":["Thesis (Ph.D.)-- Wichita State University, College of Liberal Arts and Sciences, Department of Chemistry and Biochemistry"],"dc:description.abstract":["This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements."],"dc:identifier.other":["d22020s"],"dc:identifier.uri":["https://soar.wichita.edu/handle/10057/24967"],"dc:language.iso":["en_US"],"dc:publisher":["Wichita State University"],"dc:rights":["© Copyright 2022 by Ammar Mohamed Abdelghafar Abdelgawad All Rights Reserved"],"dc:title":["Synthesis and characterization of polymer nanocomposite materials for advanced application"],"dc:type":["Dissertation"]},"updated_at":"2026-08-21T16:50:55Z"}