{"id":{"repo_id":"wfu","oai_identifier":"oai:wakespace.lib.wfu.edu:10339/59312"},"canonical_url":"https://search.dev.ndltd.org/etd/wfu/oai:wakespace.lib.wfu.edu:10339/59312","repository":{"repo_id":"wfu","name":"Wake Forest University","base_url":"https://wakespace.lib.wfu.edu/oai/request"},"display":{"title":"Structure-Function Relationships in Organic Charge-Transfer Complexes","abstract":"Organic charge-transfer complexes are ordered combinations of charge-donating (D) and charge-accepting (A) compounds. The proximity of the D and A units results in a partial degree of ionicity and a band structure that is a hybrid of the parent compounds, allowing the complex to exhibit interesting physical characteristics. These include metallicity, ambipolar semiconductivity, photoconductivity, ferroelectricity, and more. The focus of this work is to identify several structure-function relationships in charge-transfer complexes pertaining to organic field-effect transistors (OFETs). The materials of focus in these studies are perylene- 7,7,8,8-tetracyanoquinodimethane (perylene-TCNQ), dibenzotetrathiafulvalene-TCNQ (DBTTF-TCNQ), and stilbene-F4TCNQ.","abstract_html":"Organic charge-transfer complexes are ordered combinations of charge-donating (D) and charge-accepting (A) compounds. The proximity of the D and A units results in a partial degree of ionicity and a band structure that is a hybrid of the parent compounds, allowing the complex to exhibit interesting physical characteristics. These include metallicity, ambipolar semiconductivity, photoconductivity, ferroelectricity, and more. The focus of this work is to identify several structure-function relationships in charge-transfer complexes pertaining to organic field-effect transistors (OFETs). The materials of focus in these studies are perylene- 7,7,8,8-tetracyanoquinodimethane (perylene-TCNQ), dibenzotetrathiafulvalene-TCNQ (DBTTF-TCNQ), and stilbene-F4TCNQ.","abstract_has_math":false,"creators":["Goetz, Katelyn Patricia"],"institution":"Wake Forest University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2016,"date_issued":"2016","date_published":"2016","updated_at":"2026-07-27T22:02:05Z","subjects":["Charge-Transfer Complexes"],"languages":["en"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10339/59312","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Goetz, Katelyn Patricia"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-05-21T08:35:50Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2017-05-20T08:30:08Z"]},{"key":"dc:date.issued","label":"Date","values":["2016"]},{"key":"dc:publisher","label":"Institution","values":["Wake Forest University"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Charge-Transfer Complexes"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10339/59312"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Organic charge-transfer complexes are ordered combinations of charge-donating (D) and charge-accepting (A) compounds. The proximity of the D and A units results in a partial degree of ionicity and a band structure that is a hybrid of the parent compounds, allowing the complex to exhibit interesting physical characteristics. These include metallicity, ambipolar semiconductivity, photoconductivity, ferroelectricity, and more. The focus of this work is to identify several structure-function relationships in charge-transfer complexes pertaining to organic field-effect transistors (OFETs). The materials of focus in these studies are perylene- 7,7,8,8-tetracyanoquinodimethane (perylene-TCNQ), dibenzotetrathiafulvalene-TCNQ (DBTTF-TCNQ), and stilbene-F4TCNQ."]},{"key":"dc:title","label":"Title","values":["Structure-Function Relationships in Organic Charge-Transfer Complexes"]}]}],"canonical_facts":{"dc:creator":["Goetz, Katelyn Patricia"],"dc:date.accessioned":["2016-05-21T08:35:50Z"],"dc:date.available":["2017-05-20T08:30:08Z"],"dc:date.issued":["2016"],"dc:description.abstract":["Organic charge-transfer complexes are ordered combinations of charge-donating (D) and charge-accepting (A) compounds. The proximity of the D and A units results in a partial degree of ionicity and a band structure that is a hybrid of the parent compounds, allowing the complex to exhibit interesting physical characteristics. These include metallicity, ambipolar semiconductivity, photoconductivity, ferroelectricity, and more. The focus of this work is to identify several structure-function relationships in charge-transfer complexes pertaining to organic field-effect transistors (OFETs). The materials of focus in these studies are perylene- 7,7,8,8-tetracyanoquinodimethane (perylene-TCNQ), dibenzotetrathiafulvalene-TCNQ (DBTTF-TCNQ), and stilbene-F4TCNQ."],"dc:identifier.uri":["http://hdl.handle.net/10339/59312"],"dc:language.iso":["en"],"dc:publisher":["Wake Forest University"],"dc:subject":["Charge-Transfer Complexes"],"dc:title":["Structure-Function Relationships in Organic Charge-Transfer Complexes"],"dc:type":["Dissertation"]},"updated_at":"2026-07-27T22:02:05Z"}