{"id":{"repo_id":"wfu","oai_identifier":"oai:wakespace.lib.wfu.edu:10339/36145"},"canonical_url":"https://search.dev.ndltd.org/etd/wfu/oai:wakespace.lib.wfu.edu:10339/36145","repository":{"repo_id":"wfu","name":"Wake Forest University","base_url":"https://wakespace.lib.wfu.edu/oai/request"},"display":{"title":"2-Silicon-Substituted 1,3-Dienes: Participants in Diels-Alder Chemistry and Metal-Mediated Processes","abstract":"Two of the major focuses in current synthetic organic chemistry are asymmetric carbon-carbon bond forming processes and catalytic one-pot reactions. Two processes that are of interest to our research are the Diels-Alder reaction and transition-metal-catalyzed cross-coupling reactions. Issues that arise in these processes include poor efficiency and poor stereoselectivity. My dissertation research has centered around the synthesis and use of 2-silicon-substituted 1,3-dienes to alleviate these problems. These dienes, whether utilized as reagents or intermediates, serve as synthons for less reactive/selective 2-aryl 1,3-dienes.","abstract_html":"Two of the major focuses in current synthetic organic chemistry are asymmetric carbon-carbon bond forming processes and catalytic one-pot reactions. Two processes that are of interest to our research are the Diels-Alder reaction and transition-metal-catalyzed cross-coupling reactions. Issues that arise in these processes include poor efficiency and poor stereoselectivity. My dissertation research has centered around the synthesis and use of 2-silicon-substituted 1,3-dienes to alleviate these problems. These dienes, whether utilized as reagents or intermediates, serve as synthons for less reactive/selective 2-aryl 1,3-dienes.","abstract_has_math":false,"creators":["Junker, Christopher Sean"],"institution":"Wake Forest University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2011,"date_issued":"2011","date_published":"2011","updated_at":"2026-07-27T22:01:20Z","subjects":["Cross-Coupling"],"languages":["en"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10339/36145","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Junker, Christopher Sean"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2011-09-08T08:35:48Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2013-09-08T08:30:07Z"]},{"key":"dc:date.issued","label":"Date","values":["2011"]},{"key":"dc:publisher","label":"Institution","values":["Wake Forest University"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Cross-Coupling"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10339/36145"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Two of the major focuses in current synthetic organic chemistry are asymmetric carbon-carbon bond forming processes and catalytic one-pot reactions. Two processes that are of interest to our research are the Diels-Alder reaction and transition-metal-catalyzed cross-coupling reactions. Issues that arise in these processes include poor efficiency and poor stereoselectivity. My dissertation research has centered around the synthesis and use of 2-silicon-substituted 1,3-dienes to alleviate these problems. These dienes, whether utilized as reagents or intermediates, serve as synthons for less reactive/selective 2-aryl 1,3-dienes."]},{"key":"dc:title","label":"Title","values":["2-Silicon-Substituted 1,3-Dienes: Participants in Diels-Alder Chemistry and Metal-Mediated Processes"]}]}],"canonical_facts":{"dc:creator":["Junker, Christopher Sean"],"dc:date.accessioned":["2011-09-08T08:35:48Z"],"dc:date.available":["2013-09-08T08:30:07Z"],"dc:date.issued":["2011"],"dc:description.abstract":["Two of the major focuses in current synthetic organic chemistry are asymmetric carbon-carbon bond forming processes and catalytic one-pot reactions. Two processes that are of interest to our research are the Diels-Alder reaction and transition-metal-catalyzed cross-coupling reactions. Issues that arise in these processes include poor efficiency and poor stereoselectivity. My dissertation research has centered around the synthesis and use of 2-silicon-substituted 1,3-dienes to alleviate these problems. These dienes, whether utilized as reagents or intermediates, serve as synthons for less reactive/selective 2-aryl 1,3-dienes."],"dc:identifier.uri":["http://hdl.handle.net/10339/36145"],"dc:language.iso":["en"],"dc:publisher":["Wake Forest University"],"dc:subject":["Cross-Coupling"],"dc:title":["2-Silicon-Substituted 1,3-Dienes: Participants in Diels-Alder Chemistry and Metal-Mediated Processes"],"dc:type":["Dissertation"]},"updated_at":"2026-07-27T22:01:20Z"}