{"id":{"repo_id":"washington","oai_identifier":"oai:digital.lib.washington.edu:1773/50734"},"canonical_url":"https://search.dev.ndltd.org/etd/washington/oai:digital.lib.washington.edu:1773/50734","repository":{"repo_id":"washington","name":"University of Washington","base_url":"https://digital.lib.washington.edu/server/oai/request"},"display":{"title":"Myers-Inspired Selenium-Mediated Isomerization: An Efficient Generation of Contra-Thermodynamic Allenes and Alkenes with the Potential for Reductive Deamination of Primary Amines and Metal-Free Hydrogenation of Dienes","abstract":"Novel methods of catalytic metal-free isomerization reactions are scarce. By combining precedents in reductive defunctionalization reactions, coupled with previous advances in selenium-catalyzed C-N bond forming reactions, we have developed a contemporary but efficient manner of reaching contra-thermodynamic isomers of alkenes and alkynes. These isomerizations follow a well envisioned mechanistic path that may lead to further development in reductive deamination reactions, such as the reduction of primary amines such as anilines, and diamines to monoenes.","abstract_html":"Novel methods of catalytic metal-free isomerization reactions are scarce. By combining precedents in reductive defunctionalization reactions, coupled with previous advances in selenium-catalyzed C-N bond forming reactions, we have developed a contemporary but efficient manner of reaching contra-thermodynamic isomers of alkenes and alkynes. 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By combining precedents in reductive defunctionalization reactions, coupled with previous advances in selenium-catalyzed C-N bond forming reactions, we have developed a contemporary but efficient manner of reaching contra-thermodynamic isomers of alkenes and alkynes. These isomerizations follow a well envisioned mechanistic path that may lead to further development in reductive deamination reactions, such as the reduction of primary amines such as anilines, and diamines to monoenes."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Myers-Inspired Selenium-Mediated Isomerization: An Efficient Generation of Contra-Thermodynamic Allenes and Alkenes with the Potential for Reductive Deamination of Primary Amines and Metal-Free Hydrogenation of Dienes"]}]}],"canonical_facts":{"dc:contributor.advisor":["Michael, Forrest E"],"dc:creator":["Landing, Samuel Dane"],"dc:date.accessioned":["2023-09-27T17:18:47Z"],"dc:date.available":["2023-09-27T17:18:47Z"],"dc:date.issued":["2023-09-27"],"dc:description":["Thesis (Master's)--University of Washington, 2023"],"dc:description.abstract":["Novel methods of catalytic metal-free isomerization reactions are scarce. By combining precedents in reductive defunctionalization reactions, coupled with previous advances in selenium-catalyzed C-N bond forming reactions, we have developed a contemporary but efficient manner of reaching contra-thermodynamic isomers of alkenes and alkynes. These isomerizations follow a well envisioned mechanistic path that may lead to further development in reductive deamination reactions, such as the reduction of primary amines such as anilines, and diamines to monoenes."],"dc:format.mimetype":["application/pdf"],"dc:identifier.other":["Landing_washington_0250O_25861.pdf"],"dc:identifier.uri":["http://hdl.handle.net/1773/50734"],"dc:language.iso":["en_US"],"dc:rights":["none"],"dc:subject":["contra-thermodynamic","isomerization","meyers'","olefin","selenium","Organic chemistry"],"dc:title":["Myers-Inspired Selenium-Mediated Isomerization: An Efficient Generation of Contra-Thermodynamic Allenes and Alkenes with the Potential for Reductive Deamination of Primary Amines and Metal-Free Hydrogenation of Dienes"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T05:58:12Z"}