Emerging stable isotope techniques in hydrothermal research: new methods applied to carbonates and hydrous minerals in ore deposits and geothermal fields
type: CreativeWork
description: Over the last 70 years, stable isotopes have provided critical insight into the processes governing transfer of mass and energy through geologic systems. Significantly, isotopic signals in minerals reflect conditions of crystallisation, and subsequent alteration history. In hydrothermal systems, isotope tools have been applied to interpret fluid origin, temperature, and interaction with host rock. The research carried out here makes use of emerging techniques to measure hydrogen, oxygen, carbon, and clumped isotopes in carbonates and hydrous minerals. This work encompasses three themes: (i) Development of new laser spectroscopy approaches for measuring δ2H and δ18O in hydrous minerals (ii) Testing carbonate clumped isotope thermometry in geothermal fields and mineral deposits (iii) Application of carbonate and hydrous mineral isotope tools in epithermal precious metal deposits A novel approach to measure δ2H and δ18O in hydrous minerals is presented in Chapters 3-4. Measurement was carried out on phyllosilicates, hydrous sulphates, and multimineralic whole rock assay pulps using a custom-built thermal dehydration-dehydroxylation Off-Axis Integrated Cavity Output Spectroscopy (TD-OA-ICOS) system. The δ2H methodology presented is equal to isotope ratio mass spectrometry in terms of speed and precision, but considerably lower in cost. This work represents the first hydrogen isotope measurements made by a laser spectroscopy system for serpentine, muscovite, sericite, talc, and biotite. The TD-OA-ICOS method was subsequently applied to measure δ18O in microvolumes of water, gypsum hydration water, and the hydroxyl component of phyllosilicate minerals (Chapter 4). Intramineral oxygen isotope fractionation values in kaolinite and muscovite, determined by comparison of δ18OOH measured by TD-OA-ICOS with δ18Osilicate measured by fluorination, are similar to existing constraints. Refinement of this approach should be carried out to test the relationship between formation temp…
abstract: Over the last 70 years, stable isotopes have provided critical insight into the processes governing transfer of mass and energy through geologic systems. Significantly, isotopic signals in minerals reflect conditions of crystallisation, and subsequent alteration history. In hydrothermal systems, isotope tools have been applied to interpret fluid origin, temperature, and interaction with host rock. The research carried out here makes use of emerging techniques to measure hydrogen, oxygen, carbon, and clumped isotopes in carbonates and hydrous minerals. This work encompasses three themes: (i) Development of new laser spectroscopy approaches for measuring δ2H and δ18O in hydrous minerals (ii) Testing carbonate clumped isotope thermometry in geothermal fields and mineral deposits (iii) Application of carbonate and hydrous mineral isotope tools in epithermal precious metal deposits A novel approach to measure δ2H and δ18O in hydrous minerals is presented in Chapters 3-4. Measurement was carried out on phyllosilicates, hydrous sulphates, and multimineralic whole rock assay pulps using a custom-built thermal dehydration-dehydroxylation Off-Axis Integrated Cavity Output Spectroscopy (TD-OA-ICOS) system. The δ2H methodology presented is equal to isotope ratio mass spectrometry in terms of speed and precision, but considerably lower in cost. This work represents the first hydrogen isotope measurements made by a laser spectroscopy system for serpentine, muscovite, sericite, talc, and biotite. The TD-OA-ICOS method was subsequently applied to measure δ18O in microvolumes of water, gypsum hydration water, and the hydroxyl component of phyllosilicate minerals (Chapter 4). Intramineral oxygen isotope fractionation values in kaolinite and muscovite, determined by comparison of δ18OOH measured by TD-OA-ICOS with δ18Osilicate measured by fluorination, are similar to existing constraints. Refinement of this approach should be carried out to test the relationship between formation temp…
author: Mering, John
keywords: stable isotope, geothermal, hydrothermal, ore deposit, clumped isotopes, hydrous minerals, carbonates, laser spectroscopy, epithermal, Waihi, Taupo volcanic zone, Antamina, skarn, Comstock
license: https://researchcommons.waikato.ac.nz/bitstreams/e08aa419-35fc-4e2f-89f2-2c9babe52d2e/download
date published: 2019
date modified: 2026-07-24T05:57:36Z
provider: University Waikato
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: The University of Waikato