Microwave spectroscopy of pentafluorosulfanylisocynate

The microwave spectrum of pentafluorosulfanylisocyanate, SF₅ -N = C = 0 has been investigated in the 8 GHz to 26 GHz region using a conventional Stark modulated spectrometer. Twenty six transitions have been assigned. A rigid rotor fit was performed by using low J transitions. The spectroscopic constants obtained are A = 2707.69 MHz, B = 1191.22 MHz, and C = 1191.13 MHz. These constants are close to those determined by the electron diffraction study on pentafluorosulfanylisocyanate and to this extent tend to support the bent -N = C = 0 structure as proposed by the electron diffraction study.

Name thesis:degree_name

M.S.

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Chemistry

Department dc:contributor.department

Chemistry

Grantor dc:publisher

Virginia Polytechnic Institute and State University

Year dc:date.issued

1986

Author dc:creator

• Tho, Lee-Lee

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en_US

Handle dc:identifier.uri

http://hdl.handle.net/10919/94478

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/94478