Analysis of Ionomer-coated Carbon Nanofiber for use in PEM Fuel Cell Catalyst Layers

The typical catalyst layer structure for proton exchange membrane (PEM) fuel cells has changed little over the last two decades. A new electrode design with improved control over factors such as ionic and electrical pathways, porosity, and catalyst placement, could allow the application of less expensive catalyst alternatives. In this work, a novel electrode design based on ionomer-coated carbon nanofibers is proposed and studied. Governing equations for this design were established, and a mathematical model was created and solved using MATLAB to predict the performance of the new electrode design. A parametric study was performed to identify the design variables that had the most significant effect on performance. The best performing catalyst layer design studied with this model produces a current density of 1.1 A cm-2 at 600 mV which is better than state-of-the-art cathode designs. The results offer insight into the performance of ionomer-coated carbon nanofiber catalyst layers and can guide the fabrication and testing of these promising catalyst layer structures.

Name thesis:degree_name

Master of Science

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Mechanical Engineering

Department dc:contributor.department

Mechanical Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

2019

Author dc:creator

• Garrabrant, Austin Joseph

Chair dc:contributor.committeechair

• Ellis, Michael W.

Committee members dc:contributor.committeemember

• Moore, Robert Bowen
• von Spakovsky, Michael R.

• PEMFC
• Fuel Cell
• cathode design
• electrode
• carbon nanofiber

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Dc Identifier Other

vt_gsexam:21491

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/92593