Virginia Tech
Desalination of Produced Water via Gas Hydrate Formation and Post Treatment
Abstract
dc:description.abstractThis study presents a two-step desalination process, in which produced water is cleaned by forming gas hydrate in it and subsequently dewatering the hydrate to remove the residual produced water trapped in between the hydrate crystals. All experiments were performed with pressure in the range of 450 to 800psi and temperature in the range of -1 to 1°C using CO? as guest molecule for the hydrate crystals. The experiments were conducted using artificial produced waters containing different amounts of NaCl, CaCl₂ and MgCl₂ at varying temperature (T) and pressure (P). The results are presented as functions of %Reduction of difference chemical elements, CO? requirements and applied T and P conditions. The impact of dewatering techniques, including centrifuge and filtration process, on gas hydrate solid product is studied. The results showed that over 99% of dissolved NaCl and MgCl2 can be removed from artificial saline water in laboratory experiments. This was achieved in a process involving a single-stage hydrate formation step, followed by a single-step solid-liquid separation (or dewatering). The results also show that the %Reduction (percentage of the concentration decrease) of artificial produced water increases with centrifugation time and rotational speed (rpm). The %Reduction was increased considerably after hydrate crystals were crushed and filtered, indicating that the artificial process water was entrapped in between the hydrate crystals. It was found also that the finer the particle size, the higher the extent of salt removal. In general, filtration was a better than centrifugation for the removal of TDS (Total Dissolved Solids).
Degree
thesis:*- Name thesis:degree_name
- Master of Science
- Level thesis:degree_level
- masters
- Discipline thesis:degree_discipline
- Mining and Minerals Engineering
- Department dc:contributor.department
- Mining and Minerals Engineering
- Grantor dc:publisher
- Virginia Tech
- Year dc:date.issued
- 2012
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Niu, Jing
- Chair dc:contributor.committeechair
-
- Yoon, Roe-Hoan
- Committee members dc:contributor.committeemember
-
- Luttrell, Gerald H.
- Adel, Gregory T.
- Gandour, Richard D.
Subjects
dc:subject × 2Rights
dc:rights- Statement dc:rights
-
- In Copyright
- Licence dc:rights.uri
- Language dc:language.iso
- en_US
Identifiers
dc:identifier.*- Dc Identifier Other
- etd-07122012-172310
- OAI identifier oai:identifier
- oai:vtechworks.lib.vt.edu:10919/76822