Virginia Tech
Evaluating the Leachability of Elements from Residuals Generated by Hydraulic Fracturing in Marcellus Shale
Abstract
dc:description.abstractThe purpose of this research was to characterize the residual solids produced from hydraulic fracturing operations in the Marcellus Shale region. Four field samples were evaluated: drilling mud, treated sludge from the chemical treatment of process water, solids from the gravity settling of produced water, and sludge solidified prior to disposal in a municipal landfill. Cement kiln dust (CKD), used for solidification, was also considered in this study. All samples were subjected to a variety of laboratory techniques to determine their elemental composition and the potential for the elements to leach from the landfill. Strong acid digestion using a 3:1 combination of nitric acid to hydrochloric acid in a microwave with closed vessels was used to determine overall elemental composition. Leaching experiments were performed with de-ionized water and acetic acid (0.57%, pH 2.88) in an attempt to respectively evaluate the effects of weak and strong fluids that might be encountered by the residuals in landfill environments. Elements were analyzed by means of ICP-MS revealing the increased tendency for alkali metals, alkaline earth metals and halogens to leach. Leachablility was further increased for metals when exposed to acidic conditions.
Degree
thesis:*- Name thesis:degree_name
- Master of Science
- Level thesis:degree_level
- masters
- Discipline thesis:degree_discipline
- Civil Engineering
- Department dc:contributor.department
- Civil and Environmental Engineering
- Grantor dc:publisher
- Virginia Tech
- Year dc:date.issued
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Swann, Christina Talbot
- Chair dc:contributor.committeechair
-
- Boardman, Gregory D.
- Committee members dc:contributor.committeemember
-
- Parks, Jeffrey L.
- Dietrich, Andrea M.
Subjects
dc:subject × 7Rights
dc:rights- Statement dc:rights
-
- In Copyright
- Licence dc:rights.uri
Identifiers
dc:identifier.*- Dc Identifier Other
- vt_gsexam:5522
- OAI identifier oai:identifier
- oai:vtechworks.lib.vt.edu:10919/73707