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Virginia Tech

Method Development for the Synthesis of Anaerobic Digester Biogas with the Laboratory Environment

Abstract

dc:description.abstract

Biogas, a gaseous mixture produced during decomposition of organic matter, is a renewable, easily generated and common byproduct of anaerobic digestion at wastewater treatment plants (WWTP), landfills and agricultural operations. There is growing interest in researching and utilizing the energy potential associated with its combustion. Siloxanes, a family of volatile organic silicon compounds, pose large impediments to biogas usage due to the formation and precipitation of silicon dioxide within combustion devices. Removal of siloxanes prior to combustion is therefore a growing endeavor. Research was performed to synthesize a representative gas stream produced from anaerobic digesters within WWTP. Methane, carbon dioxide and hydrogen sulfide were combined with humidity and gaseous siloxane in levels characteristically seen exiting anaerobic digesters. A methanol impinger train was utilized to sample the biogas composite. Gas chromatography-mass spectrometry (GC-MS) was used to determine gas-phase siloxane concentrations in the gas stream effluent for the purposes of confirming the generation of a consistent and reproducible biogas stream.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Environmental Engineering
Department dc:contributor.department
Civil and Environmental Engineering
Grantor dc:publisher
Virginia Tech
Year dc:date.issued
2015

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Freitas, Andrew Daniel Sanchez
Chair dc:contributor.committeechair
  • Boardman, Gregory D.
Committee members dc:contributor.committeemember
  • Cox, Steven S.
  • Bott, Charles B.

Subjects

dc:subject × 5

Rights

dc:rights
Statement dc:rights
  • In Copyright

Identifiers

dc:identifier.*
Dc Identifier Other
vt_gsexam:4443
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/51388

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Freitas, Andrew Daniel Sanchez. Method Development for the Synthesis of Anaerobic Digester Biogas with the Laboratory Environment. masters thesis, Virginia Tech, 2015. http://hdl.handle.net/10919/51388