Removal of dissolved organic matter from surface waters by coagulation with trivalent iron

The molecular size, charge, and solubility, distributions of natural DOC in raw and treated surface waters were investigated to determine the types of organic compounds removed by coagulation and settling. The distribution of organic precursors that react with chlorine to form organic halide compounds was also determined, along with the reaction rates. DOC removal by coagulation was size dependent. Compounds over 5,000 d were readily removed while compounds under 1,000 d were largely unaffected. Acidic and basic molecules were precipitated much more effectively than neutral ones. Both hydrophilic and hydrophobic molecules were selectively removed compared to compounds of intermediate solubility. Two groups of organic halide precursors were identified. Fulvic acids had high specific organic halide yields, and fast reaction rates with chlorine, but could be effectively removed by coagulation. Nonpolar neutral compounds were lower in molecular weight, slower to react with chlorine, and produced less organic halide, but could not be precipitated by coagulation.

Name thesis:degree_name

Ph. D.

Level thesis:degree_level

doctoral

Discipline thesis:degree_discipline

Environmental Science and Engineering

Department dc:contributor.department

Environmental Science and Engineering

Grantor dc:publisher

Virginia Polytechnic Institute and State University

Year dc:date.issued

1985

Author dc:creator

• Sinsabaugh, Robert L.

Chair dc:contributor.committeechair

• Hoehn, Robert C.

Committee members dc:contributor.committeemember

• Knocke, William R.
• Linkins, A.E.
• Novak, John
• Benfield, Fred

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Handle dc:identifier.uri

http://hdl.handle.net/10919/49777

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/49777