Effects of alloying elements upon austenite decomposition in high strength low alloy steels

The kinetics of austenite decomposition were studied in high purity Fe-0.1 C-0.4 Mn-0.3 Si-X (concentrations in weight percent, X represents 3 Ni, 1 Cr, or 0.5 Mo) steels at temperatures between 500 and 675°C. The transformation stasis phenomenon was found in the Fe-C-Mn-Si-Mo and Fe-C-Mn-Si-Ni alloys isothermally transformed at 650°C and 675°C but not in the Fe-C-Mn-Si and Fe-C-Mn-Si-Cr alloys at any of the temperatures investigated. The occurrence of transformation stasis was explained by synergistic interactions among alloying elements. The paraequilibrium model was applied to calculate the metastable fraction of ferrite in each alloy. This fraction was shown to coincide with cessation of transformation in the Mo alloy transformed at 600°C. Transformation stasis was found in both the Ni and the Mo alloys isothermally reacted at 650°C and 675°C. The interactions among Mn, Si, and Mo as well as interactions among Mn, Si, and Ni appear to decrease the threshold concentrations for occurrence of transformation stasis in Fe-C-Mn-Si systems. The segregation of Mn and Mo to the α/γ boundary assisted by Si was suggested to enhance the drag force and led to transformation stasis. In the Ni alloy, lower driving force for ferite formation by addition of Ni could be responsible for occurrence of transformation stasis.

Name thesis:degree_name

Master of Science

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Materials Science and Engineering

Department dc:contributor.department

Materials Science and Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

1992

Author dc:creator

• Chen, Jhewn-Kuang

Chair dc:contributor.committeechair

• Reynolds, William T. Jr.

Committee members dc:contributor.committeemember

• Houska, Charles R.
• Desu, Seshu B.
• Aning, Alexander O.

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Dc Identifier Other

etd-10102009-020227

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/45126