{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/42148"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/42148","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"Evaluation of the use of ferrous iron for chlorite removal under alkaline pH conditions","abstract":"Chlorine dioxide has gained much attention for use as a possible alternative disinfectant in water treatment plants due to concerns regarding trihalomethane formation in drinking waters which utilize chlorine as the primary disinfectant and the strict regulations regarding THM's and THMFP (MCL of 0.080 mg/L for TTHMs) (Pontius, 1993). Although the use of Cl02 as a disinfectant prevents the formation of THM's, concern exists regarding the potential health risks due to the disinfection-by-products of chlorite and chlorate. The main objective of this project was to study the removal of chlorite by reaction with ferrous iron under elevated pH conditions. The stoichiometry of the reaction was evaluated under the following conditions: solution pH of 6.0 to 10.0, 02(aq) concentration of 0.5 to 10 mg/L, and solution DOC concentrations of 0 to 15 mg/L. Mass balances were conducted to define the speciation of the oxychlorine residuals associated with the reduction of Cl02 by Fe(II).","abstract_html":"Chlorine dioxide has gained much attention for use as a possible alternative disinfectant in water treatment plants due to concerns regarding trihalomethane formation in drinking waters which utilize chlorine as the primary disinfectant and the strict regulations regarding THM's and THMFP (MCL of 0.080 mg/L for TTHMs) (Pontius, 1993). Although the use of Cl02 as a disinfectant prevents the formation of THM's, concern exists regarding the potential health risks due to the disinfection-by-products of chlorite and chlorate. The main objective of this project was to study the removal of chlorite by reaction with ferrous iron under elevated pH conditions. The stoichiometry of the reaction was evaluated under the following conditions: solution pH of 6.0 to 10.0, 02(aq) concentration of 0.5 to 10 mg/L, and solution DOC concentrations of 0 to 15 mg/L. Mass balances were conducted to define the speciation of the oxychlorine residuals associated with the reduction of Cl02 by Fe(II).","abstract_has_math":false,"creators":["Hurst, Gregory H."],"institution":"Virginia Tech","degree_name":"Master of Science","degree_level":"masters","degree_discipline":"Environmental Planning","degree_department":"Environmental Engineering","school":null,"contributors":[],"advisors":[],"committee_chairs":["Knocke, William R."],"committee_members":["Dietrich, Andrea M.","Little, John C."],"year":1994,"date_issued":"1994-09-14","date_published":"1994-09-14","updated_at":"2026-07-22T22:18:42Z","subjects":[],"languages":["en"],"rights":["In Copyright"],"rights_urls":["http://rightsstatements.org/vocab/InC/1.0/"],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-04182009-041317"],"render_values":[{"text":"etd-04182009-041317","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10919/42148","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.committeechair","label":"Committee Chair","values":["Knocke, William R."]},{"key":"dc:contributor.committeemember","label":"Committee Member","values":["Dietrich, Andrea M.","Little, John C."]},{"key":"dc:contributor.department","label":"Department","values":["Environmental Engineering"]},{"key":"dc:creator","label":"Author","values":["Hurst, Gregory H."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-03-14T21:34:07Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-03-14T21:34:07Z","2009-04-18"]},{"key":"dc:date.issued","label":"Date","values":["1994-09-14"]},{"key":"dc:publisher","label":"Institution","values":["Virginia Tech"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"dc:type.dcmitype","label":"Dc Type Dcmitype","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Environmental Planning"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Virginia Polytechnic Institute and State University"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["In Copyright"]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-04182009-041317"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10919/42148"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Chlorine dioxide has gained much attention for use as a possible alternative disinfectant in water treatment plants due to concerns regarding trihalomethane formation in drinking waters which utilize chlorine as the primary disinfectant and the strict regulations regarding THM's and THMFP (MCL of 0.080 mg/L for TTHMs) (Pontius, 1993). Although the use of Cl02 as a disinfectant prevents the formation of THM's, concern exists regarding the potential health risks due to the disinfection-by-products of chlorite and chlorate. The main objective of this project was to study the removal of chlorite by reaction with ferrous iron under elevated pH conditions. The stoichiometry of the reaction was evaluated under the following conditions: solution pH of 6.0 to 10.0, 02(aq) concentration of 0.5 to 10 mg/L, and solution DOC concentrations of 0 to 15 mg/L. Mass balances were conducted to define the speciation of the oxychlorine residuals associated with the reduction of Cl02 by Fe(II)."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Master of Science"]},{"key":"dc:format.medium","label":"Dc Format Medium","values":["BTD"]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Evaluation of the use of ferrous iron for chlorite removal under alkaline pH conditions"]}]}],"canonical_facts":{"dc:contributor.committeechair":["Knocke, William R."],"dc:contributor.committeemember":["Dietrich, Andrea M.","Little, John C."],"dc:contributor.department":["Environmental Engineering"],"dc:creator":["Hurst, Gregory H."],"dc:date.accessioned":["2014-03-14T21:34:07Z"],"dc:date.available":["2014-03-14T21:34:07Z","2009-04-18"],"dc:date.issued":["1994-09-14"],"dc:description.abstract":["Chlorine dioxide has gained much attention for use as a possible alternative disinfectant in water treatment plants due to concerns regarding trihalomethane formation in drinking waters which utilize chlorine as the primary disinfectant and the strict regulations regarding THM's and THMFP (MCL of 0.080 mg/L for TTHMs) (Pontius, 1993). Although the use of Cl02 as a disinfectant prevents the formation of THM's, concern exists regarding the potential health risks due to the disinfection-by-products of chlorite and chlorate. The main objective of this project was to study the removal of chlorite by reaction with ferrous iron under elevated pH conditions. The stoichiometry of the reaction was evaluated under the following conditions: solution pH of 6.0 to 10.0, 02(aq) concentration of 0.5 to 10 mg/L, and solution DOC concentrations of 0 to 15 mg/L. Mass balances were conducted to define the speciation of the oxychlorine residuals associated with the reduction of Cl02 by Fe(II)."],"dc:description.degree":["Master of Science"],"dc:format.medium":["BTD"],"dc:format.mimetype":["application/pdf"],"dc:identifier.other":["etd-04182009-041317"],"dc:identifier.uri":["http://hdl.handle.net/10919/42148"],"dc:language.iso":["en"],"dc:publisher":["Virginia Tech"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:title":["Evaluation of the use of ferrous iron for chlorite removal under alkaline pH conditions"],"dc:type":["Thesis"],"dc:type.dcmitype":["Text"],"thesis:degree_discipline":["Environmental Planning"],"thesis:degree_level":["masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["Virginia Polytechnic Institute and State University"]},"updated_at":"2026-07-22T22:18:42Z"}