Processing of composite fibers based on polypropylene and a thermotropic liquid crystalline polymer

Isotactic polypropylene (PP) was reinforced with Vectra B950 (VB), a thermotropic liquid crystalline polymer (TLCP), in two novel fiber spinning processes. In one process, a single VB melt stream was surrounded by a sheath of PP in a manner comparable to a wire coating process just prior to melt spinning to generate fibers possessing a sheath-core structure. The other process involved the distribution of continuous VB melt streams within a separately plasticated PP melt to form a composite melt which was drawn to create matrix-fibril fibers consisting of a PP matrix in situ reinforced with VB fibrils. Both processes allow polymers with non-overlapping processing temperatures to be combined and melt spun to form composite fibers. The effect of fiber draw ratio on the tensile mechanical properties was assessed for composite fibers reinforced with 50 wt.% (39 vol.%) VB. Numerical simulations of the non-isothermal fiber drawing processes and an investigation of fiber morphology were undertaken in order to explain the mechanical properties. The matrix-fibril (in situ) reinforced fibers were woven into fabric preforms. The preforms, pre-wetted with PP, were used to fabricate orthotropic composites, and the mechanical performance and formability of these composites was evaluated.

Name thesis:degree_name

Master of Science

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Chemical Engineering

Department dc:contributor.department

Chemical Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

1995

Author dc:creator

• Robertson, Christopher G.

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Dc Identifier Other

etd-01172009-063538

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/40661