The partial oxidation of propene to acrolein over single-crystal Cu₂O

The partial oxidation of propene (CH₂=CHCH3) to acrolein (CH₂=CHCHO) has been studied over Cu₂0(100) and (111) single crystal surfaces. Propene adsorption under ultrahigh vacuum conditions yields no significant oxidation products, but the propene desorption temperatures are sensitive to the structural differences in the surfaces. Propene adsorption at atmospheric pressure followed by thermal desorption in ultrahigh vacuum demonstrates that propene may be activated at higher pressures. Over the nonpolar Cu₂0(111) surface, lattice oxygen insertion occurs at 300 K and 1 atm. with the formation of the σ-bonded allyl intermediate. Once formed, this specie is stable in ultrahigh vacuum and produces acrolein during TDS via a reaction-limited process. A comparison of these data with studies of allyl alcohol decomposition over Cu₂O surfaces indicate that the σ-bonded intermediate is surface allyloxy (CH₂=CH-CH₂0-) which dehydrogenates to acrolein via hydride elimination on the carbon α to the oxygen. Thus, oxygen insertion precedes the final hydrogen abstraction in the partial oxidation pathway. Propene is also observed during allyl alcohol decomposition indicating that the transformation of the π-allyl to the σ-allyl (allyloxy) during propene oxidation is reversible. The structure sensitivity of the propene oxidation reaction is demonstrated by the lack of acrolein production from the Cu-terminated, Cu₂0(100) surface following 1 atm. propene exposures. The origin of the structure sensitivity is related to the absence of coordinately-unsaturated lattice oxygen anions on the (100) surface.

Name thesis:degree_name

Ph. D.

Level thesis:degree_level

doctoral

Discipline thesis:degree_discipline

Chemical Engineering

Department dc:contributor.department

Chemical Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

1991

Author dc:creator

• Schulz, Kirk H.

Chair dc:contributor.committeechair

• Cox, David

Committee members dc:contributor.committeemember

• Merola, Joseph S.
• Dillard, John G.
• Davis, Mark E.
• Anderson, Mark R.

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Dc Identifier Other

etd-02262007-095951

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/37413