Direct Force Measurement between Surfaces Coated with Hydrophobic Polymers in Aqueous Solutions and the Separation of Mixed Plastics by Flotation

Froth floatation is an important process used in the mining industry for separating minerals from each other. The separation process is based on rendering a selected mineral hydrophobic using an appropriate hydrophobizing reagent (collector), so that it can selectively attach onto the surfaces of a rising stream of air bubbles. Thus, controlling the hydrophobicity of the minerals to be separated from each other is of critical importance in flotation. If one wishes to separate plastics from each other by flotation, however, it would be necessary to render a selected plastic hydrophilic and leave the others hydrophobic. In the present work, the possibility of separating common plastics from each other by flotation has been explored. While water contact angle is the most widely used measure of the hydrophobicity of a solid, it does not give the information on the kinetics of flotation. Therefore, the forces acting between the surfaces coated with different hydrophobic polymers (or plastics) in water were measured using the Atomic Force Microscope (AFM). The results obtained with polystyrene, polymethylmethacryrate (PMMA), polypropylene (PP), and Teflon showed the existence of long-range attractive forces (or hydrophobic force) that cannot be explained by the classical DLVO theory. The surface force measurements were conducted in pure water and in solutions of surfactant (alkyltrimethylammonium chloride) and a salt (NaCl). In pure water, the attractive forces were much stronger than van der Waals force. In the presence of the surfactant and NaCl, the long-range attraction decreased with increasing concentration and the alkyl chain length. A series of contact angle measurements were conducted to determine the hydrophobicity of polystyrene (PS), polyvinyl chlorite (PVC), and polymethylmethacrylate (PMMA) in the presence of different wetting agents (surfactants). The results show the possibility of separating plastics from each other by flotation, and a series of microflotation tests conducted on PS and PVC showed promising results.

Name thesis:degree_name

Master of Science

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Mining and Minerals Engineering

Department dc:contributor.department

Mining and Minerals Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

2008

Author dc:creator

• Ma, Nini

Chair dc:contributor.committeechair

• Yoon, Roe-Hoan

Committee members dc:contributor.committeemember

• Adel, Gregory T.
• Luttrell, Gerald H.

• plastic recycling
• flotation of plastics
• DLVO theory
• froth flotation
• contact angle
• surface force
• hydrophobic polymers

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Dc Identifier Other

etd-12222008-163505

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/36399