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Virginia Tech

Control of Surface Chemistry of Gold, Pyrite and Pyrrhotite

Abstract

dc:description.abstract

Removing pyrite from coal and pyrrhotite from pentlandite play a critical role in coal and nickel production, respectively, to meet the stringent restriction on SO2 emission. The present project investigates first the mechanism of xanthate adsorption on gold using Atomic Force Microscope (AFM), then the depression of pyrite and pyrrhotite using the synthetic polymers developed by Cytec Industries. The results show that for xanthate/gold system, dixanthogen is the only species that renders the surface hydrophobic. Chemisorbed xanthate is observed on the gold surface but is hydrophilic. The synthetic polymers may adsorb on pyrite and pyrrhotite possibly through the hydrophobic interaction between the hydrophobic moiety of the polymer and the mineral surface that has been hydrophobized by collector adsorption. The hydrophilic moieties of the polymer are exposed to the aqueous phase and render the surface hydrophilic.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Mining and Minerals Engineering
Department dc:contributor.department
Mining and Minerals Engineering
Grantor dc:publisher
Virginia Tech
Year dc:date.issued
1997

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Chen, Xianguo
Chair dc:contributor.committeechair
  • Yoon, Roe-Hoan
Committee members dc:contributor.committeemember
  • Luttrell, Gerald H.
  • Adel, Gregory T.
  • Karmis, Michael E.

Subjects

dc:subject × 4

Rights

dc:rights
Statement dc:rights
  • In Copyright

Identifiers

dc:identifier.*
Dc Identifier Other
etd-110398-115411
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/35583

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Chen, Xianguo. Control of Surface Chemistry of Gold, Pyrite and Pyrrhotite. masters thesis, Virginia Tech, 1997. http://hdl.handle.net/10919/35583