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Virginia Tech

Charge Control of Ionic Polymers

Abstract

dc:description.abstract

Ionomeric polymer metal composites can be used as transducers characterized by high strain and low force. They are created by bonding a thin conductive electrode to the surfaces of an ionomeric polymer. Much of the work in the past has focused on using a voltage across the thickness of the polymer to produce mechanical motion. That work has often demonstrated that the mechanism of transduction within the polymer was associated with the accumulation of charge in the polymer. This thesis will discuss the use of current as a means to better control the accumulation of charge. Better control of the charge will provide more reliable control of the mechanical motion of the polymer. The data presented in this thesis demonstrates that the response of an ionomeric polymer to a current input is repeatable. The repeatability is a desirable result; however, using current to actuate the polymers also produces back relaxation in the response. Examination of the back relaxation reveals a low frequency non-linearity. The nonlinearity is quantified by the fact that the gain associated with the back relaxation does not increase linearly with an increase in input current. There is also a change in the response at certain voltage thresholds. For example, when the voltage across the polymer exceeds 3 V, the rate of back relaxation increases. The repeatability of the response will aid in implementing reliable control of the polymer, but the non-linearities in the back relaxation will provide a considerable challenge in developing a model to be used in control.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Mechanical Engineering
Department dc:contributor.department
Mechanical Engineering
Grantor dc:publisher
Virginia Tech
Year dc:date.issued
2005

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Robinson, Walter Junkin
Chair dc:contributor.committeechair
  • Leo, Donald J.
Committee members dc:contributor.committeemember
  • Robertshaw, Harry H.
  • Inman, Daniel J.

Subjects

dc:subject × 3

Rights

dc:rights
Statement dc:rights
  • In Copyright

Identifiers

dc:identifier.*
Dc Identifier Other
etd-08022005-095016
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/34308

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Robinson, Walter Junkin. Charge Control of Ionic Polymers. masters thesis, Virginia Tech, 2005. http://hdl.handle.net/10919/34308