{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/33627"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/33627","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"Performance Characteriztion and Modeling of a Passive Direct Methanol Fuel Cell (DMFC) over a Range of Operating Temperatures and Relative Humidities","abstract":"As the world begins to focus more and more on new and more effective means of energy production, fuel cells become increasingly more popular. While different fuel cells are already found in industry today, the direct methanol fuel cell (DMFC) is becoming an increasingly more probable means for portable power production. In such applications a passive air breathing direct methanol fuel cell would be ideal. However, successful use of the passive DMFC in such applications requires that the fuel cell be capable of operating at various temperatures and relative humidities. A passive air breathing direct methanol fuel cell was developed and manufactured for this study. This work studied the effects of varying relative humidity and temperature over a probable range of operating conditions for small scale portable power applications on the performance of the fuel cell, both in relation to power production and fuel consumption. Potentiostatic, electrochemical impedance spectroscopy, and polarization tests were performed in order to characterize the performance of the fuel cell. Additionally, a one dimensional steady state isothermal mass transport model was developed to provide insight to the behavior of the fuel cell. The experimental data and model results show that increasing the fuel cell temperature and decreasing the ambient relative humidity increases the current production capabilities of the fuel cell. Further, the experimental data suggests that the major problem hindering current production in passive air breathing direct methanol fuel cells is flooding of the cathode diffusion layer.","abstract_html":"As the world begins to focus more and more on new and more effective means of energy production, fuel cells become increasingly more popular. While different fuel cells are already found in industry today, the direct methanol fuel cell (DMFC) is becoming an increasingly more probable means for portable power production. In such applications a passive air breathing direct methanol fuel cell would be ideal. However, successful use of the passive DMFC in such applications requires that the fuel cell be capable of operating at various temperatures and relative humidities. A passive air breathing direct methanol fuel cell was developed and manufactured for this study. This work studied the effects of varying relative humidity and temperature over a probable range of operating conditions for small scale portable power applications on the performance of the fuel cell, both in relation to power production and fuel consumption. Potentiostatic, electrochemical impedance spectroscopy, and polarization tests were performed in order to characterize the performance of the fuel cell. Additionally, a one dimensional steady state isothermal mass transport model was developed to provide insight to the behavior of the fuel cell. The experimental data and model results show that increasing the fuel cell temperature and decreasing the ambient relative humidity increases the current production capabilities of the fuel cell. Further, the experimental data suggests that the major problem hindering current production in passive air breathing direct methanol fuel cells is flooding of the cathode diffusion layer.","abstract_has_math":false,"creators":["Woolard, David Glenn"],"institution":"Virginia Tech","degree_name":"Master of Science","degree_level":"masters","degree_discipline":"Mechanical Engineering","degree_department":"Mechanical Engineering","school":null,"contributors":[],"advisors":[],"committee_chairs":["Ellis, Michael W."],"committee_members":["von Spakovsky, Michael R.","Nelson, Douglas J."],"year":2010,"date_issued":"2010-06-04","date_published":"2010-06-04","updated_at":"2026-07-22T22:18:58Z","subjects":["direct methanol fuel cell","fuel cell","DMFC","air breathing"],"languages":["en"],"rights":["In Copyright"],"rights_urls":["http://rightsstatements.org/vocab/InC/1.0/"],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-06172010-205801"],"render_values":[{"text":"etd-06172010-205801","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10919/33627","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.committeechair","label":"Committee Chair","values":["Ellis, Michael W."]},{"key":"dc:contributor.committeemember","label":"Committee Member","values":["von Spakovsky, Michael R.","Nelson, Douglas J."]},{"key":"dc:contributor.department","label":"Department","values":["Mechanical Engineering"]},{"key":"dc:creator","label":"Author","values":["Woolard, David Glenn"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-03-14T20:40:10Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-03-14T20:40:10Z","2010-07-13"]},{"key":"dc:date.issued","label":"Date","values":["2010-06-04"]},{"key":"dc:publisher","label":"Institution","values":["Virginia Tech"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Mechanical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Virginia Polytechnic Institute and State University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["direct methanol fuel cell","fuel cell","DMFC","air breathing"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["In Copyright"]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-06172010-205801"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10919/33627"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["As the world begins to focus more and more on new and more effective means of energy production, fuel cells become increasingly more popular. While different fuel cells are already found in industry today, the direct methanol fuel cell (DMFC) is becoming an increasingly more probable means for portable power production. In such applications a passive air breathing direct methanol fuel cell would be ideal. However, successful use of the passive DMFC in such applications requires that the fuel cell be capable of operating at various temperatures and relative humidities. A passive air breathing direct methanol fuel cell was developed and manufactured for this study. This work studied the effects of varying relative humidity and temperature over a probable range of operating conditions for small scale portable power applications on the performance of the fuel cell, both in relation to power production and fuel consumption. Potentiostatic, electrochemical impedance spectroscopy, and polarization tests were performed in order to characterize the performance of the fuel cell. Additionally, a one dimensional steady state isothermal mass transport model was developed to provide insight to the behavior of the fuel cell. The experimental data and model results show that increasing the fuel cell temperature and decreasing the ambient relative humidity increases the current production capabilities of the fuel cell. Further, the experimental data suggests that the major problem hindering current production in passive air breathing direct methanol fuel cells is flooding of the cathode diffusion layer."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Master of Science"]},{"key":"dc:title","label":"Title","values":["Performance Characteriztion and Modeling of a Passive Direct Methanol Fuel Cell (DMFC) over a Range of Operating Temperatures and Relative Humidities"]}]}],"canonical_facts":{"dc:contributor.committeechair":["Ellis, Michael W."],"dc:contributor.committeemember":["von Spakovsky, Michael R.","Nelson, Douglas J."],"dc:contributor.department":["Mechanical Engineering"],"dc:creator":["Woolard, David Glenn"],"dc:date.accessioned":["2014-03-14T20:40:10Z"],"dc:date.available":["2014-03-14T20:40:10Z","2010-07-13"],"dc:date.issued":["2010-06-04"],"dc:description.abstract":["As the world begins to focus more and more on new and more effective means of energy production, fuel cells become increasingly more popular. While different fuel cells are already found in industry today, the direct methanol fuel cell (DMFC) is becoming an increasingly more probable means for portable power production. In such applications a passive air breathing direct methanol fuel cell would be ideal. However, successful use of the passive DMFC in such applications requires that the fuel cell be capable of operating at various temperatures and relative humidities. A passive air breathing direct methanol fuel cell was developed and manufactured for this study. This work studied the effects of varying relative humidity and temperature over a probable range of operating conditions for small scale portable power applications on the performance of the fuel cell, both in relation to power production and fuel consumption. Potentiostatic, electrochemical impedance spectroscopy, and polarization tests were performed in order to characterize the performance of the fuel cell. Additionally, a one dimensional steady state isothermal mass transport model was developed to provide insight to the behavior of the fuel cell. The experimental data and model results show that increasing the fuel cell temperature and decreasing the ambient relative humidity increases the current production capabilities of the fuel cell. Further, the experimental data suggests that the major problem hindering current production in passive air breathing direct methanol fuel cells is flooding of the cathode diffusion layer."],"dc:description.degree":["Master of Science"],"dc:identifier.other":["etd-06172010-205801"],"dc:identifier.uri":["http://hdl.handle.net/10919/33627"],"dc:language.iso":["en"],"dc:publisher":["Virginia Tech"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:subject":["direct methanol fuel cell","fuel cell","DMFC","air breathing"],"dc:title":["Performance Characteriztion and Modeling of a Passive Direct Methanol Fuel Cell (DMFC) over a Range of Operating Temperatures and Relative Humidities"],"dc:type":["Thesis"],"thesis:degree_discipline":["Mechanical Engineering"],"thesis:degree_level":["masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["Virginia Polytechnic Institute and State University"]},"updated_at":"2026-07-22T22:18:58Z"}