{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/28796"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/28796","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"A study of the displacement of halogen from chlorinated heteroaromatic azines by dialkali salts of benzoylacetone, disodio salts of certain 2-hydroxy-4-methylpyrimidines, and the methylsulfinyl carbanion","abstract":"Halogenated monocyclic and bicyclic heteroaromatic azines, possessing a six or ten w-electron system and one or two ring nitrogens, have been shown to undergo nucleophilic displacement of halide ion with a variety of nucleophiles. A detailed review of the relative reactivity of compounds of these classes, as well as halogenated heteroaromatic azines containing as many as four nitrogen atoms has appeared.","abstract_html":"Halogenated monocyclic and bicyclic heteroaromatic azines, possessing a six or ten w-electron system and one or two ring nitrogens, have been shown to undergo nucleophilic displacement of halide ion with a variety of nucleophiles. A detailed review of the relative reactivity of compounds of these classes, as well as halogenated heteroaromatic azines containing as many as four nitrogen atoms has appeared.","abstract_has_math":false,"creators":["Greene, James Carson"],"institution":"Virginia Tech","degree_name":"Ph. D.","degree_level":"doctoral","degree_discipline":"Chemistry","degree_department":"Chemistry","school":null,"contributors":[],"advisors":[],"committee_chairs":["Wolfe, James F."],"committee_members":["Clifford, Alan F.","Ogliaruso, Michael A.","Dillard, John G.","Ward, Thomas C."],"year":1971,"date_issued":"1971-11-01","date_published":"1971-11-01","updated_at":"2026-07-22T22:19:21Z","subjects":["nucleophilic substitution reaction mechanisms"],"languages":["en"],"rights":["In Copyright"],"rights_urls":["http://rightsstatements.org/vocab/InC/1.0/"],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-08252008-162325"],"render_values":[{"text":"etd-08252008-162325","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10919/28796","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.committeechair","label":"Committee Chair","values":["Wolfe, James F."]},{"key":"dc:contributor.committeemember","label":"Committee Member","values":["Clifford, Alan F.","Ogliaruso, Michael A.","Dillard, John G.","Ward, Thomas C."]},{"key":"dc:contributor.department","label":"Department","values":["Chemistry"]},{"key":"dc:creator","label":"Author","values":["Greene, James Carson"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-03-14T20:15:41Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-03-14T20:15:41Z","2008-08-25"]},{"key":"dc:date.issued","label":"Date","values":["1971-11-01"]},{"key":"dc:publisher","label":"Institution","values":["Virginia Tech"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]},{"key":"dc:type.dcmitype","label":"Dc Type Dcmitype","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["doctoral"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph. D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Virginia Polytechnic Institute and State University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["nucleophilic substitution reaction mechanisms"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["In Copyright"]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-08252008-162325"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10919/28796"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Halogenated monocyclic and bicyclic heteroaromatic azines, possessing a six or ten w-electron system and one or two ring nitrogens, have been shown to undergo nucleophilic displacement of halide ion with a variety of nucleophiles. A detailed review of the relative reactivity of compounds of these classes, as well as halogenated heteroaromatic azines containing as many as four nitrogen atoms has appeared."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Ph. D."]},{"key":"dc:format.medium","label":"Dc Format Medium","values":["BTD"]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["A study of the displacement of halogen from chlorinated heteroaromatic azines by dialkali salts of benzoylacetone, disodio salts of certain 2-hydroxy-4-methylpyrimidines, and the methylsulfinyl carbanion"]}]}],"canonical_facts":{"dc:contributor.committeechair":["Wolfe, James F."],"dc:contributor.committeemember":["Clifford, Alan F.","Ogliaruso, Michael A.","Dillard, John G.","Ward, Thomas C."],"dc:contributor.department":["Chemistry"],"dc:creator":["Greene, James Carson"],"dc:date.accessioned":["2014-03-14T20:15:41Z"],"dc:date.available":["2014-03-14T20:15:41Z","2008-08-25"],"dc:date.issued":["1971-11-01"],"dc:description.abstract":["Halogenated monocyclic and bicyclic heteroaromatic azines, possessing a six or ten w-electron system and one or two ring nitrogens, have been shown to undergo nucleophilic displacement of halide ion with a variety of nucleophiles. A detailed review of the relative reactivity of compounds of these classes, as well as halogenated heteroaromatic azines containing as many as four nitrogen atoms has appeared."],"dc:description.degree":["Ph. D."],"dc:format.medium":["BTD"],"dc:format.mimetype":["application/pdf"],"dc:identifier.other":["etd-08252008-162325"],"dc:identifier.uri":["http://hdl.handle.net/10919/28796"],"dc:language.iso":["en"],"dc:publisher":["Virginia Tech"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:subject":["nucleophilic substitution reaction mechanisms"],"dc:title":["A study of the displacement of halogen from chlorinated heteroaromatic azines by dialkali salts of benzoylacetone, disodio salts of certain 2-hydroxy-4-methylpyrimidines, and the methylsulfinyl carbanion"],"dc:type":["Dissertation"],"dc:type.dcmitype":["Text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["doctoral"],"thesis:degree_name":["Ph. D."],"thesis:institution_name":["Virginia Polytechnic Institute and State University"]},"updated_at":"2026-07-22T22:19:21Z"}