Structure and Ozone Decomposition Reactivity of Supported Manganese Oxide Catalysts

Manganese oxide catalysts supported on Al₂O₃, ZrO₂, TiO₂ and SiO₂ supports were used to study the effect of support on ozone decomposition kinetics. X-ray diffraction (XRD), in-situ laser Raman spectroscopy, temperature programmed oxygen desorption, surface area measurements, extended and near edge x-ray absorption fine structure (EXAFS and NEXAFS) showed that the manganese oxide was highly dispersed on the surface of the supports. EXAFS spectra suggest that the manganese active centers on all of the surfaces were surrounded by five oxygen atoms. These metal centers were of a mononuclear type for the Al₂O₃ supported catalyst and multinuclear for the other supports. NEXAFS spectra for the catalysts showed a chemical shift to lower energy and an intensity change in the L-edge features which followed the trend Al₂O₃ > ZrO₂ > TiO₂ > SiO₂. The trends provided insights into the positive role of available empty electronic states required in the reduction step of a redox reaction. The catalysts were tested for their ozone decomposition reactivity and reaction rates had a fractional order dependency (n < 1) with ozone partial pressure. The apparent activation energies for the reaction was low (3-15 kJ/mol). The support influenced the desorption step (a reduction step) and this effect manifested itself in the pre-exponential factor of the rate constant for desorption. Trends for this pre-exponential factor correlated with trends in NEXAFS features and reflected the ease of electron donation from the adsorbed species to the active center.

Name thesis:degree_name

Ph. D.

Level thesis:degree_level

doctoral

Discipline thesis:degree_discipline

Chemical Engineering

Department dc:contributor.department

Chemical Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

2001

Author dc:creator

• Radhakrishnan, Rakesh

Chair dc:contributor.committeechair

• Oyama, Shigeo Ted

Committee members dc:contributor.committeemember

• Gibbs, Gerald V.
• Davis, Richey M.
• Cox, David F.
• Dillard, John G.

• Decomposition
• Oxygen Chemisorption
• Kinetics
• Temperature Programmed Desorption
• Ozone
• Raman Spectroscopy
• Manganese oxides
• Mechanism
• Ab initio
• X-ray Absorption Fine Structure Spectroscopy

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Dc Identifier Other

etd-01252001-125957

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/26033