Analytical and Computational Micromechanics Analysis of the Effects of Interphase Regions, Orientation, and Clustering on the Effective Coefficient of Thermal Expansion of Carbon Nanotube-Polymer Nanocomposites

Analytic and computational micromechanics techniques based on the composite cylinders method and the finite element method, respectively, have been used to determine the effective coefficient of thermal expansion (CTE) of carbon nanotube-epoxy nanocomposites containing aligned nanotubes. Both techniques have been used in a parametric study of the influence of interphase stiffness and interphase CTE on the effective CTE of the nanocomposites. For both the axial and transverse CTE of aligned nanotube nanocomposites with and without interphase regions, the computational and analytic micromechanics techniques were shown to give similar results. The Mori-Tanka method has been used to account for the effect of randomly oriented fibers. Analytic and computational micromechanics techniques have also been used to assess the effects of clustering and clustering with interphase on the effective CTE components. Clustering is observed to have a minimal impact on the effective axial CTE of the nanocomposite and a 3-10%. However, there is a combined effect with clustering and one of the interphase layers.

Name thesis:degree_name

Master of Science

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Ocean Engineering

Department dc:contributor.department

Aerospace and Ocean Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

2013

Author dc:creator

• Stephens, Skylar Nicholas

Chair dc:contributor.committeechair

• Seidel, Gary D.

Committee members dc:contributor.committeemember

• Hughes, Owen F.
• Brown, Alan J.

• multiscale
• carbon nanotube
• thermal expansion
• interphase
• bundling
• orientation
• micromechanics

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Dc Identifier Other

vt_gsexam:708

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/23216