{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/110220"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/110220","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"Studies in the synthesis of n-butyl strontium","abstract":"1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound.","abstract_html":"1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound.","abstract_has_math":false,"creators":["Kuck, John F. 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Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["M.S."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Studies in the synthesis of n-butyl strontium"]}]}],"canonical_facts":{"dc:contributor.department":["Chemistry"],"dc:creator":["Kuck, John F. R."],"dc:date.accessioned":["2022-05-24T17:21:43Z"],"dc:date.available":["2022-05-24T17:21:43Z"],"dc:date.issued":["1940"],"dc:description.abstract":["1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound."],"dc:description.degree":["M.S."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["http://hdl.handle.net/10919/110220"],"dc:language.iso":["en"],"dc:publisher":["Virginia Agricultural and Mechanical College and Polytechnic Institute"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:title":["Studies in the synthesis of n-butyl strontium"],"dc:type":["Thesis"],"dc:type.dcmitype":["Text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["masters"],"thesis:degree_name":["M.S."],"thesis:institution_name":["Virginia Agricultural and Mechanical College and Polytechnic Institute"]},"updated_at":"2026-07-22T22:20:17Z"}