{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/106111"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/106111","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"The synthesis of 10-(4-hydroxymethylphenyl)-1,2-Benzanthracene","abstract":"A. The alcohol, 10-(4’-hydroxymethylphenyl)-1,2-benzanthracene, was prepared by the reduction or 10-(4’-carboxyphenyl)- 1,2- benzanthracene. The structure or the alcohol was proven by: (1) Ultraviolet spectra (2) Infrared spectra (3) Elementary analysis (4) Preparation or the benzoate B. The preparation of the Grignard reagent of 10-(4’-bromophenyl)-1,2-benzanthracene was unsuccessful. An explanation of this anomaly was not discovered. C. The Grignard reagent or 2-(1-naphthylmethyl)-chloro-benzene was prepared by the use or tetrahydrofuran and \"entrainment\" with methyl iodide.","abstract_html":"A. The alcohol, 10-(4’-hydroxymethylphenyl)-1,2-benzanthracene, was prepared by the reduction or 10-(4’-carboxyphenyl)- 1,2- benzanthracene. The structure or the alcohol was proven by: (1) Ultraviolet spectra (2) Infrared spectra (3) Elementary analysis (4) Preparation or the benzoate B. The preparation of the Grignard reagent of 10-(4’-bromophenyl)-1,2-benzanthracene was unsuccessful. An explanation of this anomaly was not discovered. C. The Grignard reagent or 2-(1-naphthylmethyl)-chloro-benzene was prepared by the use or tetrahydrofuran and "entrainment" with methyl iodide.","abstract_has_math":false,"creators":["Lewis, Claude Irenius"],"institution":"Virginia Polytechnic Institute","degree_name":"M.S.","degree_level":"masters","degree_discipline":"Chemistry","degree_department":"Chemistry","school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1959,"date_issued":"1959","date_published":"1959","updated_at":"2026-07-22T22:19:31Z","subjects":[],"languages":["en"],"rights":["In Copyright"],"rights_urls":["http://rightsstatements.org/vocab/InC/1.0/"],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10919/106111","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.department","label":"Department","values":["Chemistry"]},{"key":"dc:creator","label":"Author","values":["Lewis, Claude Irenius"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2021-10-26T20:10:10Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2021-10-26T20:10:10Z"]},{"key":"dc:date.issued","label":"Date","values":["1959"]},{"key":"dc:publisher","label":"Institution","values":["Virginia Polytechnic Institute"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"dc:type.dcmitype","label":"Dc Type Dcmitype","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.S."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Virginia Polytechnic Institute"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["In Copyright"]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10919/106111"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["A. The alcohol, 10-(4’-hydroxymethylphenyl)-1,2-benzanthracene, was prepared by the reduction or 10-(4’-carboxyphenyl)- 1,2- benzanthracene. The structure or the alcohol was proven by: (1) Ultraviolet spectra (2) Infrared spectra (3) Elementary analysis (4) Preparation or the benzoate B. The preparation of the Grignard reagent of 10-(4’-bromophenyl)-1,2-benzanthracene was unsuccessful. An explanation of this anomaly was not discovered. C. The Grignard reagent or 2-(1-naphthylmethyl)-chloro-benzene was prepared by the use or tetrahydrofuran and \"entrainment\" with methyl iodide."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["M.S."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["The synthesis of 10-(4-hydroxymethylphenyl)-1,2-Benzanthracene"]}]}],"canonical_facts":{"dc:contributor.department":["Chemistry"],"dc:creator":["Lewis, Claude Irenius"],"dc:date.accessioned":["2021-10-26T20:10:10Z"],"dc:date.available":["2021-10-26T20:10:10Z"],"dc:date.issued":["1959"],"dc:description.abstract":["A. The alcohol, 10-(4’-hydroxymethylphenyl)-1,2-benzanthracene, was prepared by the reduction or 10-(4’-carboxyphenyl)- 1,2- benzanthracene. The structure or the alcohol was proven by: (1) Ultraviolet spectra (2) Infrared spectra (3) Elementary analysis (4) Preparation or the benzoate B. The preparation of the Grignard reagent of 10-(4’-bromophenyl)-1,2-benzanthracene was unsuccessful. An explanation of this anomaly was not discovered. C. The Grignard reagent or 2-(1-naphthylmethyl)-chloro-benzene was prepared by the use or tetrahydrofuran and \"entrainment\" with methyl iodide."],"dc:description.degree":["M.S."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["http://hdl.handle.net/10919/106111"],"dc:language.iso":["en"],"dc:publisher":["Virginia Polytechnic Institute"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:title":["The synthesis of 10-(4-hydroxymethylphenyl)-1,2-Benzanthracene"],"dc:type":["Thesis"],"dc:type.dcmitype":["Text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["masters"],"thesis:degree_name":["M.S."],"thesis:institution_name":["Virginia Polytechnic Institute"]},"updated_at":"2026-07-22T22:19:31Z"}