{"id":{"repo_id":"vt","oai_identifier":"oai:vtechworks.lib.vt.edu:10919/104591"},"canonical_url":"https://search.dev.ndltd.org/etd/vt/oai:vtechworks.lib.vt.edu:10919/104591","repository":{"repo_id":"vt","name":"Virginia Tech","base_url":"https://vtechworks.lib.vt.edu/oai/request"},"display":{"title":"The reaction of monochloromethyl ether with organometallic compounds","abstract":"1. The reactions of monochlormethyl ether with the magnesium cadmium and zinc derivatives of normal propyl and isopropyl halides were investigated. 2. In both the normal propyl and iso-propyl aeries, the yields of the expected condensation products RCH₂OCH₃ appeared in the order RMgX>R₂Zn>R₂Cd. 3. The primary organometallic compounds reacted with monochlormethyl ether in higher yields than did the corresponding secondary compounds. 4. A new method was developed for preparing a zinc-copper couple by heating a mixture of zinc dust and powdered cupric citrate under an atmosphere of nitrogen. 5. This method gave a couple superior in laboratory use to the zinc-copper couples how generally employed.","abstract_html":"1. The reactions of monochlormethyl ether with the magnesium cadmium and zinc derivatives of normal propyl and isopropyl halides were investigated. 2. In both the normal propyl and iso-propyl aeries, the yields of the expected condensation products RCH₂OCH₃ appeared in the order RMgX>R₂Zn>R₂Cd. 3. The primary organometallic compounds reacted with monochlormethyl ether in higher yields than did the corresponding secondary compounds. 4. A new method was developed for preparing a zinc-copper couple by heating a mixture of zinc dust and powdered cupric citrate under an atmosphere of nitrogen. 5. This method gave a couple superior in laboratory use to the zinc-copper couples how generally employed.","abstract_has_math":false,"creators":["Tang, Philip Jen-chien"],"institution":"Virginia Tech","degree_name":"Master of Science","degree_level":"masters","degree_discipline":"Chemistry","degree_department":"Chemistry","school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1953,"date_issued":"1953","date_published":"1953","updated_at":"2026-07-22T22:19:39Z","subjects":["Organometallic compounds."],"languages":[],"rights":["In Copyright"],"rights_urls":["http://rightsstatements.org/vocab/InC/1.0/"],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-07102010-020021"],"render_values":[{"text":"etd-07102010-020021","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10919/104591","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.department","label":"Department","values":["Chemistry"]},{"key":"dc:creator","label":"Author","values":["Tang, Philip Jen-chien"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2021-08-06T17:23:32Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2021-08-06T17:23:32Z","2010-07-10"]},{"key":"dc:date.issued","label":"Date","values":["1953"]},{"key":"dc:publisher","label":"Institution","values":["Virginia Tech"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Virginia Polytechnic Institute"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Organometallic compounds."]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["In Copyright"]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["etd-07102010-020021"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10919/104591"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["1. The reactions of monochlormethyl ether with the magnesium cadmium and zinc derivatives of normal propyl and isopropyl halides were investigated. 2. In both the normal propyl and iso-propyl aeries, the yields of the expected condensation products RCH₂OCH₃ appeared in the order RMgX>R₂Zn>R₂Cd. 3. The primary organometallic compounds reacted with monochlormethyl ether in higher yields than did the corresponding secondary compounds. 4. A new method was developed for preparing a zinc-copper couple by heating a mixture of zinc dust and powdered cupric citrate under an atmosphere of nitrogen. 5. This method gave a couple superior in laboratory use to the zinc-copper couples how generally employed."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Master of Science"]},{"key":"dc:format.medium","label":"Dc Format Medium","values":["BTD"]},{"key":"dc:title","label":"Title","values":["The reaction of monochloromethyl ether with organometallic compounds"]}]}],"canonical_facts":{"dc:contributor.department":["Chemistry"],"dc:creator":["Tang, Philip Jen-chien"],"dc:date.accessioned":["2021-08-06T17:23:32Z"],"dc:date.available":["2021-08-06T17:23:32Z","2010-07-10"],"dc:date.issued":["1953"],"dc:description.abstract":["1. The reactions of monochlormethyl ether with the magnesium cadmium and zinc derivatives of normal propyl and isopropyl halides were investigated. 2. In both the normal propyl and iso-propyl aeries, the yields of the expected condensation products RCH₂OCH₃ appeared in the order RMgX>R₂Zn>R₂Cd. 3. The primary organometallic compounds reacted with monochlormethyl ether in higher yields than did the corresponding secondary compounds. 4. A new method was developed for preparing a zinc-copper couple by heating a mixture of zinc dust and powdered cupric citrate under an atmosphere of nitrogen. 5. This method gave a couple superior in laboratory use to the zinc-copper couples how generally employed."],"dc:description.degree":["Master of Science"],"dc:format.medium":["BTD"],"dc:identifier.other":["etd-07102010-020021"],"dc:identifier.uri":["http://hdl.handle.net/10919/104591"],"dc:publisher":["Virginia Tech"],"dc:rights":["In Copyright"],"dc:rights.uri":["http://rightsstatements.org/vocab/InC/1.0/"],"dc:subject":["Organometallic compounds."],"dc:title":["The reaction of monochloromethyl ether with organometallic compounds"],"dc:type":["Thesis"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["Virginia Polytechnic Institute"]},"updated_at":"2026-07-22T22:19:39Z"}