Infrared investigation of some octahedral organometalic [sic] carbonyls

Electrochemical and infrared spectral data for a number of octahedral systems of the type LM(CO)₅ (M=Cr, Mo) and W; L=pyridine and quinoline), L₂M(CO)₄ (M=Cr, Mo, and W; L₂ =ethylenediamine, (pyridine)₂, and bipyridyl), (LM(CO)₄)₂ (M=Cr, Mo, and W; L=As(CH₃)₂ and P(CH₃)₂) and (LFe(CO)₃)₂ (L=SCH₃ , P(CH₃)₂ , and As(CH₃)₂) before and after electrochemical reduction are presented. Force constants are calculated using the Cotton-Kraihanzel force field and the results discussed in terms of sigma and pi-bonding. Infrared spectral data before and after electroche~ical reduction are also reported for a number of iron-olefin complexes of low symmetry.

Name thesis:degree_name

M.S.

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Chemistry

Department dc:contributor.department

Chemistry

Grantor dc:publisher

Virginia Polytechnic Institute

Year dc:date.issued

1968

Author dc:creator

• Wieczorek, Leonard

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Handle dc:identifier.uri

http://hdl.handle.net/10919/101408

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/101408