{"id":{"repo_id":"vcu","oai_identifier":"oai:scholarscompass.vcu.edu:etd-1442"},"canonical_url":"https://search.dev.ndltd.org/etd/vcu/oai:scholarscompass.vcu.edu:etd-1442","repository":{"repo_id":"vcu","name":"Virginia Commonwealth University","base_url":"https://scholarscompass.vcu.edu/do/oai/"},"display":{"title":"Novel Shear-Thinning of Aged PDMS/Fumed Silica Admixtures and Properties of Related Silicone Elastomers","abstract":"Fumed silica filler has long been used to structurally reinforce silicone elastomers. Unfortunately, the combination of as little as a few weight percent of untreated fumed silica nanoparticles [uFSN] with a siloxane polymer, such as PDMS, forms a difficult to process waxy solid admixture that even long periods of high shear mixing will not thin. In the course of the current work it was noted that after a period of storage certain solid admixtures would become viscous liquids when subjected to additional high shear mixing. It was further found that the required aging period could be decreased if the admixture storage temperature were increased. The only known interaction of PDMS and uFSN at moderate conditions is the adsorption of polymer on filler, and this interaction is also known to occur more quickly at higher temperature. This study examines the relationship between polymer adsorption and admixture liquefaction. Further, the mechanical properties of cured elastomers containing liquefied admixtures are examined to assess the degree of reinforcement that these materials afford.","abstract_html":"Fumed silica filler has long been used to structurally reinforce silicone elastomers. Unfortunately, the combination of as little as a few weight percent of untreated fumed silica nanoparticles [uFSN] with a siloxane polymer, such as PDMS, forms a difficult to process waxy solid admixture that even long periods of high shear mixing will not thin. In the course of the current work it was noted that after a period of storage certain solid admixtures would become viscous liquids when subjected to additional high shear mixing. It was further found that the required aging period could be decreased if the admixture storage temperature were increased. The only known interaction of PDMS and uFSN at moderate conditions is the adsorption of polymer on filler, and this interaction is also known to occur more quickly at higher temperature. This study examines the relationship between polymer adsorption and admixture liquefaction. Further, the mechanical properties of cured elastomers containing liquefied admixtures are examined to assess the degree of reinforcement that these materials afford.","abstract_has_math":false,"creators":["Brooke-Devlin, Wayne"],"institution":null,"degree_name":"Doctor of Philosophy","degree_level":"Dissertation","degree_discipline":"Engineering","degree_department":null,"school":null,"contributors":["Kenneth Wynne","Mark McHugh","Gary Bowlin","Gerrard Heck","Thomas Haas"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2012,"date_issued":"2012-11-29T08:00:00Z","date_published":"2012-11-29T08:00:00Z","updated_at":"2026-07-24T05:53:56Z","subjects":["silicone","fumed silica","PDMS","shear-thinning","elastomer","Engineering"],"languages":[],"rights":["© The Author"],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["https://scholarscompass.vcu.edu/etd/443"],"render_values":[{"text":"https://scholarscompass.vcu.edu/etd/443","href":"https://scholarscompass.vcu.edu/etd/443","code":true}]}]},"links":{"outbound_url":"https://doi.org/10.25772/8417-DD35","outbound_label":"DOI","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Kenneth Wynne","Mark McHugh","Gary Bowlin","Gerrard Heck","Thomas Haas"]},{"key":"dc:creator","label":"Author","values":["Brooke-Devlin, Wayne"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2017-12-12T08:00:00Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Doctor of Philosophy"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["silicone","fumed silica","PDMS","shear-thinning","elastomer","Engineering"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["© The Author"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://doi.org/10.25772/8417-DD35","https://scholarscompass.vcu.edu/etd/443"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Fumed silica filler has long been used to structurally reinforce silicone elastomers. Unfortunately, the combination of as little as a few weight percent of untreated fumed silica nanoparticles [uFSN] with a siloxane polymer, such as PDMS, forms a difficult to process waxy solid admixture that even long periods of high shear mixing will not thin. In the course of the current work it was noted that after a period of storage certain solid admixtures would become viscous liquids when subjected to additional high shear mixing. It was further found that the required aging period could be decreased if the admixture storage temperature were increased. The only known interaction of PDMS and uFSN at moderate conditions is the adsorption of polymer on filler, and this interaction is also known to occur more quickly at higher temperature. This study examines the relationship between polymer adsorption and admixture liquefaction. Further, the mechanical properties of cured elastomers containing liquefied admixtures are examined to assess the degree of reinforcement that these materials afford."]},{"key":"dc:title","label":"Title","values":["Novel Shear-Thinning of Aged PDMS/Fumed Silica Admixtures and Properties of Related Silicone Elastomers"]}]}],"canonical_facts":{"dc:contributor":["Kenneth Wynne","Mark McHugh","Gary Bowlin","Gerrard Heck","Thomas Haas"],"dc:creator":["Brooke-Devlin, Wayne"],"dc:date.available":["2017-12-12T08:00:00Z"],"dc:description.abstract":["Fumed silica filler has long been used to structurally reinforce silicone elastomers. Unfortunately, the combination of as little as a few weight percent of untreated fumed silica nanoparticles [uFSN] with a siloxane polymer, such as PDMS, forms a difficult to process waxy solid admixture that even long periods of high shear mixing will not thin. In the course of the current work it was noted that after a period of storage certain solid admixtures would become viscous liquids when subjected to additional high shear mixing. It was further found that the required aging period could be decreased if the admixture storage temperature were increased. The only known interaction of PDMS and uFSN at moderate conditions is the adsorption of polymer on filler, and this interaction is also known to occur more quickly at higher temperature. This study examines the relationship between polymer adsorption and admixture liquefaction. Further, the mechanical properties of cured elastomers containing liquefied admixtures are examined to assess the degree of reinforcement that these materials afford."],"dc:identifier":["https://doi.org/10.25772/8417-DD35","https://scholarscompass.vcu.edu/etd/443"],"dc:rights":["© The Author"],"dc:subject":["silicone","fumed silica","PDMS","shear-thinning","elastomer","Engineering"],"dc:title":["Novel Shear-Thinning of Aged PDMS/Fumed Silica Admixtures and Properties of Related Silicone Elastomers"],"thesis:degree_discipline":["Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Doctor of Philosophy"]},"updated_at":"2026-07-24T05:53:56Z"}