{"id":{"repo_id":"unt","oai_identifier":"info:ark/67531/metadc3261"},"canonical_url":"https://search.dev.ndltd.org/etd/unt/info:ark/67531/metadc3261","repository":{"repo_id":"unt","name":"University of North Texas","base_url":"https://digital.library.unt.edu/oai/"},"display":{"title":"Electrodeposition of Diamond-like Carbon Films","abstract":"Electrodeposition of diamond-like carbon (DLC) films was studied on different substrates using two different electrochemical methods. The first electrochemical method using a three-electrode system was studied to successfully deposit hydrogenated DLC films on Nickel, Copper and Brass substrates. The as-deposited films were characterized by scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FTIR) and cyclic voltammetry (CV). A variety of experimental parameters were shown to affect the deposition process. The second electrochemical method was developed for the first time to deposit hydrogen free DLC films on Ni substrates through a two-electrode system. The as-deposited films were characterized by Raman spectroscopy and FTIR. According to Raman spectra, a high fraction of diamond nanocrystals were found to form in the films. Several possible mechanisms were discussed for each deposition method. An electrochemical method was proposed to deposit boron-doped diamond films for future work.","abstract_html":"Electrodeposition of diamond-like carbon (DLC) films was studied on different substrates using two different electrochemical methods. The first electrochemical method using a three-electrode system was studied to successfully deposit hydrogenated DLC films on Nickel, Copper and Brass substrates. The as-deposited films were characterized by scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FTIR) and cyclic voltammetry (CV). A variety of experimental parameters were shown to affect the deposition process. The second electrochemical method was developed for the first time to deposit hydrogen free DLC films on Ni substrates through a two-electrode system. The as-deposited films were characterized by Raman spectroscopy and FTIR. According to Raman spectra, a high fraction of diamond nanocrystals were found to form in the films. Several possible mechanisms were discussed for each deposition method. An electrochemical method was proposed to deposit boron-doped diamond films for future work.","abstract_has_math":false,"creators":["Chen, Minhua"],"institution":"University of North Texas","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["Golden, Teresa D.","D'Souza, Nandika A.","Chyan, Oliver M. R."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2002,"date_issued":"2002-08","date_published":"2002-08","updated_at":"2026-07-24T05:34:52Z","subjects":["Thin films.","Hydrocarbons.","diamond-like carbon films","electrodeposition","SEM","Raman spectroscopy","XPS"],"languages":["English"],"rights":["Public","Copyright","Chen, Minhua","Copyright is held by the author, unless otherwise noted. All rights reserved."],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["oclc: 50591456","https://digital.library.unt.edu/ark:/67531/metadc3261/","ark: ark:/67531/metadc3261"],"render_values":[{"text":"oclc: 50591456","href":null,"code":true},{"text":"https://digital.library.unt.edu/ark:/67531/metadc3261/","href":"https://digital.library.unt.edu/ark:/67531/metadc3261/","code":true},{"text":"ark: ark:/67531/metadc3261","href":null,"code":true}]}]},"links":{"outbound_url":"https://doi.org/10.12794/metadc3261","outbound_label":"DOI","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Golden, Teresa D.","D'Souza, Nandika A.","Chyan, Oliver M. 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The second electrochemical method was developed for the first time to deposit hydrogen free DLC films on Ni substrates through a two-electrode system. The as-deposited films were characterized by Raman spectroscopy and FTIR. According to Raman spectra, a high fraction of diamond nanocrystals were found to form in the films. Several possible mechanisms were discussed for each deposition method. An electrochemical method was proposed to deposit boron-doped diamond films for future work."]},{"key":"dc:format","label":"Dc Format","values":["Text"]},{"key":"dc:title","label":"Title","values":["Electrodeposition of Diamond-like Carbon Films"]}]}],"canonical_facts":{"dc:contributor":["Golden, Teresa D.","D'Souza, Nandika A.","Chyan, Oliver M. R."],"dc:creator":["Chen, Minhua"],"dc:date":["2002-08"],"dc:description":["Electrodeposition of diamond-like carbon (DLC) films was studied on different substrates using two different electrochemical methods. The first electrochemical method using a three-electrode system was studied to successfully deposit hydrogenated DLC films on Nickel, Copper and Brass substrates. The as-deposited films were characterized by scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FTIR) and cyclic voltammetry (CV). A variety of experimental parameters were shown to affect the deposition process. The second electrochemical method was developed for the first time to deposit hydrogen free DLC films on Ni substrates through a two-electrode system. The as-deposited films were characterized by Raman spectroscopy and FTIR. According to Raman spectra, a high fraction of diamond nanocrystals were found to form in the films. Several possible mechanisms were discussed for each deposition method. An electrochemical method was proposed to deposit boron-doped diamond films for future work."],"dc:format":["Text"],"dc:identifier":["oclc: 50591456","doi: 10.12794/metadc3261","https://digital.library.unt.edu/ark:/67531/metadc3261/","ark: ark:/67531/metadc3261"],"dc:language":["English"],"dc:publisher":["University of North Texas"],"dc:rights":["Public","Copyright","Chen, Minhua","Copyright is held by the author, unless otherwise noted. All rights reserved."],"dc:subject":["Thin films.","Hydrocarbons.","diamond-like carbon films","electrodeposition","SEM","Raman spectroscopy","XPS"],"dc:title":["Electrodeposition of Diamond-like Carbon Films"],"dc:type":["Thesis or Dissertation"]},"updated_at":"2026-07-24T05:34:52Z"}