Synthesis and evaluation of rare-earth doped glasses and crystals for optical refrigeration
type: CreativeWork
description: This research focused on developing and characterizing rare-earth doped, solid-state materials for laser cooling. In particular, the work targeted the optimization of the laser-cooling efficiency in Yb3+ and Tm3+ doped fluorides. The first instance of laser-induced cooling in a Tm3+-doped crystal, BaY2F8 was reported. Cooling by 3 degrees Kelvin below ambient temperature was obtained in a single-pass pump geometry at λ = 1855 nm. Protocols were developed for materials synthesis and purification which can be applied to each component of ZBLANI:Yb3+/Tm3+ (ZrF4 — BaF2 — LaF3 — AlF3 — NaF — InF3: YbF3/TmF3) glass to enable a material with significantly reduced transition-metal impurities. A method for OH- impurity removal and ultra-drying of the metal fluorides was also improved upon. Several characterization tools were used to quantitatively and qualitatively verify purity, including inductively-coupled plasma mass spectrometry (ICP-MS). Here we found a more than 600-fold reduction in transition-metal impurities in a ZrCl2O solution. A non-contact spectroscopic technique for the measurement of laser-induced temperature changes in solids was developed. Two-band differential luminescence thermometry (TBDLT) achieved a sensitivity of ~7 mK and enabled precise measurement of the zero-crossing temperature and net quantum efficiency. Several Yb3+-doped ZBLANI glasses fabricated from precursors of varying purity and by different processes were analyzed in detail by TBDLT. Laser-induced cooling was observed at room temperature for several of the materials. A net quantum efficiency of 97.39±0.01% at 238 K was found for the best ZBLANI:1%Yb3+ laser-cooling sample produced from purified metal-fluoride precursors, and proved competitive with the best commercially procured material. The TBDLT technique enabled rapid and sensitive benchmarking of laser-cooling materials and provided critical feedback to the development and optimization of high-performance optical cryocooler material…
abstract: This research focused on developing and characterizing rare-earth doped, solid-state materials for laser cooling. In particular, the work targeted the optimization of the laser-cooling efficiency in Yb3+ and Tm3+ doped fluorides. The first instance of laser-induced cooling in a Tm3+-doped crystal, BaY2F8 was reported. Cooling by 3 degrees Kelvin below ambient temperature was obtained in a single-pass pump geometry at λ = 1855 nm. Protocols were developed for materials synthesis and purification which can be applied to each component of ZBLANI:Yb3+/Tm3+ (ZrF4 — BaF2 — LaF3 — AlF3 — NaF — InF3: YbF3/TmF3) glass to enable a material with significantly reduced transition-metal impurities. A method for OH- impurity removal and ultra-drying of the metal fluorides was also improved upon. Several characterization tools were used to quantitatively and qualitatively verify purity, including inductively-coupled plasma mass spectrometry (ICP-MS). Here we found a more than 600-fold reduction in transition-metal impurities in a ZrCl2O solution. A non-contact spectroscopic technique for the measurement of laser-induced temperature changes in solids was developed. Two-band differential luminescence thermometry (TBDLT) achieved a sensitivity of ~7 mK and enabled precise measurement of the zero-crossing temperature and net quantum efficiency. Several Yb3+-doped ZBLANI glasses fabricated from precursors of varying purity and by different processes were analyzed in detail by TBDLT. Laser-induced cooling was observed at room temperature for several of the materials. A net quantum efficiency of 97.39±0.01% at 238 K was found for the best ZBLANI:1%Yb3+ laser-cooling sample produced from purified metal-fluoride precursors, and proved competitive with the best commercially procured material. The TBDLT technique enabled rapid and sensitive benchmarking of laser-cooling materials and provided critical feedback to the development and optimization of high-performance optical cryocooler material…
author: Patterson, Wendy Marie
language: English
date published: 2010-02-09T08:00:00Z
date modified: 2026-07-24T05:26:35Z
provider: University of New Mexico
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of New Mexico

PropertyValue
property ID: Handle
value: http://hdl.handle.net/1928/10315