{"id":{"repo_id":"unlv","oai_identifier":"oai:oasis.library.unlv.edu:rtds-2280"},"canonical_url":"https://search.dev.ndltd.org/etd/unlv/oai:oasis.library.unlv.edu:rtds-2280","repository":{"repo_id":"unlv","name":"University of Nevada - Las Vegas","base_url":"https://oasis.library.unlv.edu/do/oai/"},"display":{"title":"Photofragmentation of carbonyl sulfide (Ocs) following core-shell photoexcitation and photoionization","abstract":"Mass spectroscopy is used to study the formation of cations and anions after photoexcitation and photoionization of OCS in the vicinity of the S 2p, C 1s and O 1s thresholds. Singly charged cations are produced predominantly at the pi* and Rydberg resonances while dications are major products of dissociative channels above the thresholds. At the S 2p threshold, broad Franck-Condon regions observed for Rydberg excited states manifests an apparent change in molecular bond lengths upon the excitation of S 2p electrons to Rydberg orbitals. Neutral dissociation of the pi*3/2, pi*1/2 and 4S 3/2 excited states is found to compete efficiently with electronic relaxation via Auger processes. The observation of SO+ ions at the pi* resonance indicates a strong Renner-Teller vibronic coupling of bending vibrations in the 4pi* excited states with a bent equilibrium geometry. The anions (S-, C- and O-) are observed both below and above the thresholds. The fact that the anion production is suppressed at shape resonances allows the anions to serve as a suggestive and complementary tool for identifying above-threshold structures in the OCS photoabsorption spectra. Post-collision-interaction effects in OCS and locality of the lowest unoccupied molecular orbital 4pi* at the sulfur atom are also evidenced in the anion spectra.","abstract_html":"Mass spectroscopy is used to study the formation of cations and anions after photoexcitation and photoionization of OCS in the vicinity of the S 2p, C 1s and O 1s thresholds. Singly charged cations are produced predominantly at the pi* and Rydberg resonances while dications are major products of dissociative channels above the thresholds. At the S 2p threshold, broad Franck-Condon regions observed for Rydberg excited states manifests an apparent change in molecular bond lengths upon the excitation of S 2p electrons to Rydberg orbitals. Neutral dissociation of the pi*3/2, pi*1/2 and 4S 3/2 excited states is found to compete efficiently with electronic relaxation via Auger processes. The observation of SO+ ions at the pi* resonance indicates a strong Renner-Teller vibronic coupling of bending vibrations in the 4pi* excited states with a bent equilibrium geometry. The anions (S-, C- and O-) are observed both below and above the thresholds. The fact that the anion production is suppressed at shape resonances allows the anions to serve as a suggestive and complementary tool for identifying above-threshold structures in the OCS photoabsorption spectra. Post-collision-interaction effects in OCS and locality of the lowest unoccupied molecular orbital 4pi* at the sulfur atom are also evidenced in the anion spectra.","abstract_has_math":false,"creators":["Dang, Lan Thi Ngoc"],"institution":"University of Nevada, Las Vegas","degree_name":"Master of Science (MS)","degree_level":"Thesis","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Dennis W. Lindle"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2001,"date_issued":"2001-01-01T08:00:00Z","date_published":"2001-01-01T08:00:00Z","updated_at":"2026-07-24T05:25:18Z","subjects":[],"languages":["English"],"rights":["IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/"],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["https://oasis.library.unlv.edu/rtds/1281"],"render_values":[{"text":"https://oasis.library.unlv.edu/rtds/1281","href":"https://oasis.library.unlv.edu/rtds/1281","code":true}]}]},"links":{"outbound_url":"https://doi.org/10.25669/x2yn-kmkx","outbound_label":"DOI","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Dennis W. Lindle"]},{"key":"dc:creator","label":"Author","values":["Dang, Lan Thi Ngoc"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:publisher","label":"Institution","values":["University of Nevada, Las Vegas"]},{"key":"dc:type","label":"Dc Type","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (MS)"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]},{"key":"dc:rights","label":"Dc Rights","values":["IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.25669/x2yn-kmkx","https://oasis.library.unlv.edu/rtds/1281","https://oasis.library.unlv.edu/context/rtds/article/2280/viewcontent/uc.pdf"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Mass spectroscopy is used to study the formation of cations and anions after photoexcitation and photoionization of OCS in the vicinity of the S 2p, C 1s and O 1s thresholds. Singly charged cations are produced predominantly at the pi* and Rydberg resonances while dications are major products of dissociative channels above the thresholds. At the S 2p threshold, broad Franck-Condon regions observed for Rydberg excited states manifests an apparent change in molecular bond lengths upon the excitation of S 2p electrons to Rydberg orbitals. Neutral dissociation of the pi*3/2, pi*1/2 and 4S 3/2 excited states is found to compete efficiently with electronic relaxation via Auger processes. The observation of SO+ ions at the pi* resonance indicates a strong Renner-Teller vibronic coupling of bending vibrations in the 4pi* excited states with a bent equilibrium geometry. The anions (S-, C- and O-) are observed both below and above the thresholds. The fact that the anion production is suppressed at shape resonances allows the anions to serve as a suggestive and complementary tool for identifying above-threshold structures in the OCS photoabsorption spectra. Post-collision-interaction effects in OCS and locality of the lowest unoccupied molecular orbital 4pi* at the sulfur atom are also evidenced in the anion spectra."]},{"key":"dc:format","label":"Dc Format","values":["pdf"]},{"key":"dc:title","label":"Title","values":["Photofragmentation of carbonyl sulfide (Ocs) following core-shell photoexcitation and photoionization"]}]}],"canonical_facts":{"dc:contributor":["Dennis W. Lindle"],"dc:creator":["Dang, Lan Thi Ngoc"],"dc:description.abstract":["Mass spectroscopy is used to study the formation of cations and anions after photoexcitation and photoionization of OCS in the vicinity of the S 2p, C 1s and O 1s thresholds. Singly charged cations are produced predominantly at the pi* and Rydberg resonances while dications are major products of dissociative channels above the thresholds. At the S 2p threshold, broad Franck-Condon regions observed for Rydberg excited states manifests an apparent change in molecular bond lengths upon the excitation of S 2p electrons to Rydberg orbitals. Neutral dissociation of the pi*3/2, pi*1/2 and 4S 3/2 excited states is found to compete efficiently with electronic relaxation via Auger processes. The observation of SO+ ions at the pi* resonance indicates a strong Renner-Teller vibronic coupling of bending vibrations in the 4pi* excited states with a bent equilibrium geometry. The anions (S-, C- and O-) are observed both below and above the thresholds. The fact that the anion production is suppressed at shape resonances allows the anions to serve as a suggestive and complementary tool for identifying above-threshold structures in the OCS photoabsorption spectra. Post-collision-interaction effects in OCS and locality of the lowest unoccupied molecular orbital 4pi* at the sulfur atom are also evidenced in the anion spectra."],"dc:format":["pdf"],"dc:identifier":["10.25669/x2yn-kmkx","https://oasis.library.unlv.edu/rtds/1281","https://oasis.library.unlv.edu/context/rtds/article/2280/viewcontent/uc.pdf"],"dc:language":["English"],"dc:publisher":["University of Nevada, Las Vegas"],"dc:rights":["IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/"],"dc:title":["Photofragmentation of carbonyl sulfide (Ocs) following core-shell photoexcitation and photoionization"],"dc:type":["Text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Thesis"],"thesis:degree_name":["Master of Science (MS)"]},"updated_at":"2026-07-24T05:25:18Z"}