{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/97461"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/97461","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Petrogenesis of natrocarbonatite at Ol Doinyo Lengai, East Africa—evidence from Fe and U isotope variations","abstract":"Ol Doinyo Lengai (ODL), Tanzania, is the only active carbonatite volcano on earth. Cyclical activity that consists of quiescent natrocarbonatite lava flow, explosive silicate eruption and dormancy has been observed throughout the 20th century at ODL. From 2007 to 2008, ODL explosively erupted coexisting natrocarbonatites and nephelinites. Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007-2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (𝛿56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+. U isotope results show that natrocarbonatite, has a 𝛿238U of -0.20 ‰ (relative to CRM-112A), being isotopically heavier than 8 nephelinite tephras (range from -0.32 to -0.41 ‰, relative to CRM-112A). Fe isotope results may reflect the interaction between an upward-moving carbonate-rich melt with previous emplaced crystal mush zone, during which Fe2+ preferentially enters the carbonate-rich melt and leaves Fe3+ in the remaining crystal rich mush zone. The carbonate-rich melt degases water as pressure drops causing the observed dry natrocarbonatite lava on the surface. U isotope results may be explained also as the role of melt interaction with the mush zone, with the soluble, 238U rich U(VI) dissolved in the carbonate-rich melt ultimately causing the observed heavier U isotope composition in natrocarbonatite relative to the nephelinite.","abstract_html":"Ol Doinyo Lengai (ODL), Tanzania, is the only active carbonatite volcano on earth. Cyclical activity that consists of quiescent natrocarbonatite lava flow, explosive silicate eruption and dormancy has been observed throughout the 20th century at ODL. From 2007 to 2008, ODL explosively erupted coexisting natrocarbonatites and nephelinites. Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007-2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (𝛿56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+. U isotope results show that natrocarbonatite, has a 𝛿238U of -0.20 ‰ (relative to CRM-112A), being isotopically heavier than 8 nephelinite tephras (range from -0.32 to -0.41 ‰, relative to CRM-112A). Fe isotope results may reflect the interaction between an upward-moving carbonate-rich melt with previous emplaced crystal mush zone, during which Fe2+ preferentially enters the carbonate-rich melt and leaves Fe3+ in the remaining crystal rich mush zone. The carbonate-rich melt degases water as pressure drops causing the observed dry natrocarbonatite lava on the surface. U isotope results may be explained also as the role of melt interaction with the mush zone, with the soluble, 238U rich U(VI) dissolved in the carbonate-rich melt ultimately causing the observed heavier U isotope composition in natrocarbonatite relative to the nephelinite.","abstract_has_math":false,"creators":["Zhou, Zhenhao"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"M.S.","degree_level":"Thesis","degree_discipline":"Geology","degree_department":null,"school":null,"contributors":["Lundstrom, Craig Campell"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2017,"date_issued":"2017-08-10T19:16:02Z","date_published":"2017-08-10T19:16:02Z","updated_at":"2026-07-22T22:24:34Z","subjects":["Ol Doinyo Lengai","Natrocarbonatite","Nephelinite","Isotope variations","Fluid percolation"],"languages":["en"],"rights":["Copyright 2017 Zhenhao Zhou"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/2142/97461","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Lundstrom, Craig Campell"]},{"key":"dc:creator","label":"Author","values":["Zhou, Zhenhao"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2017-08-10T19:16:02Z","2017-04-25","2017-05"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Geology"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.S."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Ol Doinyo Lengai","Natrocarbonatite","Nephelinite","Isotope variations","Fluid percolation"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2017 Zhenhao Zhou"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/97461"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Ol Doinyo Lengai (ODL), Tanzania, is the only active carbonatite volcano on earth. Cyclical activity that consists of quiescent natrocarbonatite lava flow, explosive silicate eruption and dormancy has been observed throughout the 20th century at ODL. From 2007 to 2008, ODL explosively erupted coexisting natrocarbonatites and nephelinites. Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007-2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (𝛿56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+. U isotope results show that natrocarbonatite, has a 𝛿238U of -0.20 ‰ (relative to CRM-112A), being isotopically heavier than 8 nephelinite tephras (range from -0.32 to -0.41 ‰, relative to CRM-112A). Fe isotope results may reflect the interaction between an upward-moving carbonate-rich melt with previous emplaced crystal mush zone, during which Fe2+ preferentially enters the carbonate-rich melt and leaves Fe3+ in the remaining crystal rich mush zone. The carbonate-rich melt degases water as pressure drops causing the observed dry natrocarbonatite lava on the surface. U isotope results may be explained also as the role of melt interaction with the mush zone, with the soluble, 238U rich U(VI) dissolved in the carbonate-rich melt ultimately causing the observed heavier U isotope composition in natrocarbonatite relative to the nephelinite.","Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2017-08-10 without embargo terms","The student, Zhenhao Zhou, accepted the attached license on 2017-04-24 at 16:41.","The student, Zhenhao Zhou, submitted this Thesis for approval on 2017-04-24 at 16:56.","This Thesis was approved for publication on 2017-04-25 at 15:00.","DSpace SAF Submission Ingestion Package generated from Vireo submission #11023 on 2017-08-10 at 13:45:46","Made available in DSpace on 2017-08-10T19:16:02Z (GMT). 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Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007-2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (𝛿56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+. U isotope results show that natrocarbonatite, has a 𝛿238U of -0.20 ‰ (relative to CRM-112A), being isotopically heavier than 8 nephelinite tephras (range from -0.32 to -0.41 ‰, relative to CRM-112A). Fe isotope results may reflect the interaction between an upward-moving carbonate-rich melt with previous emplaced crystal mush zone, during which Fe2+ preferentially enters the carbonate-rich melt and leaves Fe3+ in the remaining crystal rich mush zone. The carbonate-rich melt degases water as pressure drops causing the observed dry natrocarbonatite lava on the surface. U isotope results may be explained also as the role of melt interaction with the mush zone, with the soluble, 238U rich U(VI) dissolved in the carbonate-rich melt ultimately causing the observed heavier U isotope composition in natrocarbonatite relative to the nephelinite.","Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2017-08-10 without embargo terms","The student, Zhenhao Zhou, accepted the attached license on 2017-04-24 at 16:41.","The student, Zhenhao Zhou, submitted this Thesis for approval on 2017-04-24 at 16:56.","This Thesis was approved for publication on 2017-04-25 at 15:00.","DSpace SAF Submission Ingestion Package generated from Vireo submission #11023 on 2017-08-10 at 13:45:46","Made available in DSpace on 2017-08-10T19:16:02Z (GMT). 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