{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84456"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84456","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Molecule-Based Magnets Constructed From Hexacyanometalates","abstract":"Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. Also described are preparations of the cyanide building blocks K4[V(CN)6]·xH 2O, [NEt4]4[V(CN)6], K3[Cr(CN) 6]·xH2O, [NEt4]3[Cr(CN) 6]·xH2O, [NEt4]3[Ti(CN) 6]·2.5H2O, [PPN]3[Cr(CN)6], [PPN]3[Fe(CN)6], [NEt4]3[Co(CN) 6]·H2O, [PPN]3[Cr(CN)5NO], [NEt 4]CN, and [PPN]CN.","abstract_html":"Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. Also described are preparations of the cyanide building blocks K4[V(CN)6]·xH 2O, [NEt4]4[V(CN)6], K3[Cr(CN) 6]·xH2O, [NEt4]3[Cr(CN) 6]·xH2O, [NEt4]3[Ti(CN) 6]·2.5H2O, [PPN]3[Cr(CN)6], [PPN]3[Fe(CN)6], [NEt4]3[Co(CN) 6]·H2O, [PPN]3[Cr(CN)5NO], [NEt 4]CN, and [PPN]CN.","abstract_has_math":false,"creators":["Holmes, Stephen Michael"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Girolami, G.S."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:35Z","date_published":"2015-09-25T22:14:35Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Physics, Electricity and Magnetism"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9953048"],"render_values":[{"text":"(MiAaPQ)AAI9953048","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84456","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Girolami, G.S."]},{"key":"dc:creator","label":"Author","values":["Holmes, Stephen Michael"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:35Z","2000"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Physics, Electricity and Magnetism"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84456","(MiAaPQ)AAI9953048"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. Also described are preparations of the cyanide building blocks K4[V(CN)6]·xH 2O, [NEt4]4[V(CN)6], K3[Cr(CN) 6]·xH2O, [NEt4]3[Cr(CN) 6]·xH2O, [NEt4]3[Ti(CN) 6]·2.5H2O, [PPN]3[Cr(CN)6], [PPN]3[Fe(CN)6], [NEt4]3[Co(CN) 6]·H2O, [PPN]3[Cr(CN)5NO], [NEt 4]CN, and [PPN]CN.","Made available in DSpace on 2015-09-25T22:14:35Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9953048.pdf: 10279021 bytes, checksum: 50ba3a572fe659ee2b445e7ef839c0a5 (MD5) Previous issue date: 2000","Embargo set by: Seth Robbins for item 85737 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Open Restriction set for Item 85737 on 2020-06-17T18:57:11Z with date null by bran3@illinois.edu. Author gave express permission to lift restriction.","Open","298 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000."]},{"key":"dc:title","label":"Title","values":["Molecule-Based Magnets Constructed From Hexacyanometalates"]}]}],"canonical_facts":{"dc:contributor":["Girolami, G.S."],"dc:creator":["Holmes, Stephen Michael"],"dc:date":["2015-09-25T22:14:35Z","2000"],"dc:description":["Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. Also described are preparations of the cyanide building blocks K4[V(CN)6]·xH 2O, [NEt4]4[V(CN)6], K3[Cr(CN) 6]·xH2O, [NEt4]3[Cr(CN) 6]·xH2O, [NEt4]3[Ti(CN) 6]·2.5H2O, [PPN]3[Cr(CN)6], [PPN]3[Fe(CN)6], [NEt4]3[Co(CN) 6]·H2O, [PPN]3[Cr(CN)5NO], [NEt 4]CN, and [PPN]CN.","Made available in DSpace on 2015-09-25T22:14:35Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9953048.pdf: 10279021 bytes, checksum: 50ba3a572fe659ee2b445e7ef839c0a5 (MD5) Previous issue date: 2000","Embargo set by: Seth Robbins for item 85737 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Open Restriction set for Item 85737 on 2020-06-17T18:57:11Z with date null by bran3@illinois.edu. Author gave express permission to lift restriction.","Open","298 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000."],"dc:identifier":["http://hdl.handle.net/2142/84456","(MiAaPQ)AAI9953048"],"dc:language":["eng"],"dc:subject":["Physics, Electricity and Magnetism"],"dc:title":["Molecule-Based Magnets Constructed From Hexacyanometalates"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:23Z"}