{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84441"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84441","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Design and Construction of Organic Solids for Second-Order Nonlinear Optics and Nanoporosity","abstract":"194 p.","abstract_html":"194 p.","abstract_has_math":false,"creators":["Zhang, Peng"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Moore, Jeffrey S."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:31Z","date_published":"2015-09-25T22:14:31Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Chemistry, Polymer"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9921762"],"render_values":[{"text":"(MiAaPQ)AAI9921762","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84441","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Moore, Jeffrey S."]},{"key":"dc:creator","label":"Author","values":["Zhang, Peng"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:31Z","10000-01-01","1999"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Polymer"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84441","(MiAaPQ)AAI9921762"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["194 p.","In the second part of this thesis, coordination networks based on silver(I) triflate and tetrahedral ligands functionalized with nitrile groups were found to be porous. Moreover, triflate as a coordinating counterion can be utilized as a mean to increase the predictability of the network structures. Counterion effect was further tested by the crystal structures of silver(I) 3- and 4-cyanobenzenesulfonates which are one- and two-dimensional continuous networks respectively. Finally, phenyl acetylene macrocycle functionalized with nitrile groups and longer tetrahedral ligands were synthesized and the crystallization with silver(I) salts were attempted.","Made available in DSpace on 2015-09-25T22:14:31Z (GMT). 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Moreover, triflate as a coordinating counterion can be utilized as a mean to increase the predictability of the network structures. Counterion effect was further tested by the crystal structures of silver(I) 3- and 4-cyanobenzenesulfonates which are one- and two-dimensional continuous networks respectively. Finally, phenyl acetylene macrocycle functionalized with nitrile groups and longer tetrahedral ligands were synthesized and the crystallization with silver(I) salts were attempted.","Made available in DSpace on 2015-09-25T22:14:31Z (GMT). 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