{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84384"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84384","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes","abstract":"Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\\sb4$) ($\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ (19, R = Me; 20, R = $\\rm CH\\sb2SiMe\\sb3)$ react with $\\rm MeOSO\\sb2CF\\sb3$ to form $\\mu\\sb3$-thiolate complexes $\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-SMe)($\\mu\\sb3$-S) (22, R = $\\rm CH\\sb2SiMe\\sb3$; 23, R = Me). Complex 19 reacts with ($\\rm Cu(PPh\\sb3)\\sb2(NCMe)\\sb2\\rbrack\\lbrack BF\\sb4\\rbrack$ to form ($\\rm Cu(PPh\\sb3)\\sb2\\rbrack\\lbrack\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ 24.","abstract_html":"Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\\sb4$) (<span class=\"etd-inline-math\">\\rm\\{Ru(N)R\\sb2\\}\\sb3(&mu;\\sb3</span>-S)$\\sb2\\rbrack,$ (19, R = Me; 20, R = $\\rm CH\\sb2SiMe\\sb3)$ react with $\\rm MeOSO\\sb2CF\\sb3$ to form <span class=\"etd-inline-math\">&mu;\\sb3</span>-thiolate complexes <span class=\"etd-inline-math\">\\rm\\{Ru(N)R\\sb2\\}\\sb3(&mu;\\sb3</span>-SMe)(<span class=\"etd-inline-math\">&mu;\\sb3</span>-S) (22, R = $\\rm CH\\sb2SiMe\\sb3$; 23, R = Me). Complex 19 reacts with ($\\rm Cu(PPh\\sb3)\\sb2(NCMe)\\sb2\\rbrack\\lbrack BF\\sb4\\rbrack$ to form (<span class=\"etd-inline-math\">\\rm Cu(PPh\\sb3)\\sb2\\rbrack\\lbrack\\{Ru(N)R\\sb2\\}\\sb3(&mu;\\sb3</span>-S)$\\sb2\\rbrack,$ 24.","abstract_has_math":true,"creators":["Liang, Hong-Chang"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Shapley, Patricia A."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:14Z","date_published":"2015-09-25T22:14:14Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Chemistry, Inorganic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9812682"],"render_values":[{"text":"(MiAaPQ)AAI9812682","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84384","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Shapley, Patricia A."]},{"key":"dc:creator","label":"Author","values":["Liang, Hong-Chang"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:14Z","10000-01-01","1997"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Inorganic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84384","(MiAaPQ)AAI9812682"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\\sb4$) ($\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ (19, R = Me; 20, R = $\\rm CH\\sb2SiMe\\sb3)$ react with $\\rm MeOSO\\sb2CF\\sb3$ to form $\\mu\\sb3$-thiolate complexes $\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-SMe)($\\mu\\sb3$-S) (22, R = $\\rm CH\\sb2SiMe\\sb3$; 23, R = Me). Complex 19 reacts with ($\\rm Cu(PPh\\sb3)\\sb2(NCMe)\\sb2\\rbrack\\lbrack BF\\sb4\\rbrack$ to form ($\\rm Cu(PPh\\sb3)\\sb2\\rbrack\\lbrack\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ 24.","Made available in DSpace on 2015-09-25T22:14:14Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9812682.pdf: 3598558 bytes, checksum: b43533d1aba314bc6b9557aa1d52397d (MD5) Previous issue date: 1997","Embargo set by: Seth Robbins for item 85665 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","133 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997."]},{"key":"dc:title","label":"Title","values":["Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes"]}]}],"canonical_facts":{"dc:contributor":["Shapley, Patricia A."],"dc:creator":["Liang, Hong-Chang"],"dc:date":["2015-09-25T22:14:14Z","10000-01-01","1997"],"dc:description":["Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\\sb4$) ($\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ (19, R = Me; 20, R = $\\rm CH\\sb2SiMe\\sb3)$ react with $\\rm MeOSO\\sb2CF\\sb3$ to form $\\mu\\sb3$-thiolate complexes $\\rm\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-SMe)($\\mu\\sb3$-S) (22, R = $\\rm CH\\sb2SiMe\\sb3$; 23, R = Me). Complex 19 reacts with ($\\rm Cu(PPh\\sb3)\\sb2(NCMe)\\sb2\\rbrack\\lbrack BF\\sb4\\rbrack$ to form ($\\rm Cu(PPh\\sb3)\\sb2\\rbrack\\lbrack\\{Ru(N)R\\sb2\\}\\sb3(\\mu\\sb3$-S)$\\sb2\\rbrack,$ 24.","Made available in DSpace on 2015-09-25T22:14:14Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9812682.pdf: 3598558 bytes, checksum: b43533d1aba314bc6b9557aa1d52397d (MD5) Previous issue date: 1997","Embargo set by: Seth Robbins for item 85665 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","133 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997."],"dc:identifier":["http://hdl.handle.net/2142/84384","(MiAaPQ)AAI9812682"],"dc:language":["eng"],"dc:subject":["Chemistry, Inorganic"],"dc:title":["Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:23Z"}