Tetrathiometallates in Synthesis and Catalysis
Finally, Et4N[ReS4] has also been shown to react with isocyanides (MeNC, t-BuNC, CyNC) which add across the S=M=S functionality via a 3+1 cycloaddition process in the presence of S 8 to form Et4N[Re(S)(S4)(S2CNR)]. This type of cycloaddition has not been observed before for metal sulfides.
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