{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84053"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84053","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"The Structure of Solvents Confined to Metal Surfaces","abstract":"Finally, tetrabutylammonium perchlorate (TBAP) is added to DMSO. Under potential control, positive of the potential of zero charge (PZC), STM reveals the DMSO solvent structure together with the perchlorate anion. The tetrabutylammoniurn cation can not be seen due to the presence of water in the DMSO solution. With appropriate choice of electrolyte, it may now be possible, by means of in situ STM, to examine the interplay of solvent, anion, and cation at the solid/liquid interface.","abstract_html":"Finally, tetrabutylammonium perchlorate (TBAP) is added to DMSO. Under potential control, positive of the potential of zero charge (PZC), STM reveals the DMSO solvent structure together with the perchlorate anion. The tetrabutylammoniurn cation can not be seen due to the presence of water in the DMSO solution. With appropriate choice of electrolyte, it may now be possible, by means of in situ STM, to examine the interplay of solvent, anion, and cation at the solid/liquid interface.","abstract_has_math":false,"creators":["Si, Siv Keng"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Gewirth, Andrew A."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:12:37Z","date_published":"2015-09-25T22:12:37Z","updated_at":"2026-07-22T22:26:22Z","subjects":["Chemistry, Analytical"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI3023196"],"render_values":[{"text":"(MiAaPQ)AAI3023196","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84053","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Gewirth, Andrew A."]},{"key":"dc:creator","label":"Author","values":["Si, Siv Keng"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:12:37Z","10000-01-01","2001"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Analytical"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84053","(MiAaPQ)AAI3023196"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Finally, tetrabutylammonium perchlorate (TBAP) is added to DMSO. 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Under potential control, positive of the potential of zero charge (PZC), STM reveals the DMSO solvent structure together with the perchlorate anion. The tetrabutylammoniurn cation can not be seen due to the presence of water in the DMSO solution. With appropriate choice of electrolyte, it may now be possible, by means of in situ STM, to examine the interplay of solvent, anion, and cation at the solid/liquid interface.","Made available in DSpace on 2015-09-25T22:12:37Z (GMT). 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