{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84031"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84031","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Cored Dendrimers: Synthesis and Applications","abstract":"Analogous to molecular imprinted polymers, cored dendrimers were imprinted by synthesizing the structure in the presence of a template (core unit). Porphyrins were found to be useful target compounds for which to imprint cored dendrimers. The porphyrins were used as spectrophotometric probes to determine the selectivity of the cored dendrimer. Binding studies with various functionalized porphyrins and the cored dendrimer were monitored by UV/Vis spectroscopy. The results showed that these cored dendrimers were selective for porphyrins complementary in both shape and functionality to the binding site created in their interior. The binding behavior of these cored dendrimers was found to be sensitive to the conditions used for the cross-linking reaction.","abstract_html":"Analogous to molecular imprinted polymers, cored dendrimers were imprinted by synthesizing the structure in the presence of a template (core unit). Porphyrins were found to be useful target compounds for which to imprint cored dendrimers. The porphyrins were used as spectrophotometric probes to determine the selectivity of the cored dendrimer. Binding studies with various functionalized porphyrins and the cored dendrimer were monitored by UV/Vis spectroscopy. The results showed that these cored dendrimers were selective for porphyrins complementary in both shape and functionality to the binding site created in their interior. The binding behavior of these cored dendrimers was found to be sensitive to the conditions used for the cross-linking reaction.","abstract_has_math":false,"creators":["Wendland, Michael Scott"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Zimmerman, Steven C."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:12:28Z","date_published":"2015-09-25T22:12:28Z","updated_at":"2026-07-22T22:26:22Z","subjects":["Chemistry, Organic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI3017250"],"render_values":[{"text":"(MiAaPQ)AAI3017250","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84031","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Zimmerman, Steven C."]},{"key":"dc:creator","label":"Author","values":["Wendland, Michael Scott"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:12:28Z","10000-01-01","2001"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Organic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84031","(MiAaPQ)AAI3017250"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Analogous to molecular imprinted polymers, cored dendrimers were imprinted by synthesizing the structure in the presence of a template (core unit). 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Porphyrins were found to be useful target compounds for which to imprint cored dendrimers. The porphyrins were used as spectrophotometric probes to determine the selectivity of the cored dendrimer. Binding studies with various functionalized porphyrins and the cored dendrimer were monitored by UV/Vis spectroscopy. The results showed that these cored dendrimers were selective for porphyrins complementary in both shape and functionality to the binding site created in their interior. The binding behavior of these cored dendrimers was found to be sensitive to the conditions used for the cross-linking reaction.","Made available in DSpace on 2015-09-25T22:12:28Z (GMT). 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