{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/83144"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/83144","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Microbial Ecology: Spatial Aspects of Pesticide Degradation","abstract":"The influence of discontinuous water films on bioavailability of xenobiotics to soil microorganisms was examined in the third study. Comparisons were made between two scenarios for distributing the xenobiotic relative to an inoculated degrader under a range of soil moisture conditions. Spatial proximity of xenobiotic had a substantial effect on the extent of degradation, with an additional effect of moisture content. Simultaneous addition of the compound and the degrader to the soil resulted in reduced mineralization dependence on mass transfer and microbial motility. Solution phase concentrations of the compound in the vicinity of the degraders were controlled by application method, however, overall fraction of solution phase substrate was not affected, suggesting that mineralization was limited by a localized lack of solution phase substrate. The results demonstrate a possible role of physical accessibility in environmental fate of xenobiotics.","abstract_html":"The influence of discontinuous water films on bioavailability of xenobiotics to soil microorganisms was examined in the third study. Comparisons were made between two scenarios for distributing the xenobiotic relative to an inoculated degrader under a range of soil moisture conditions. Spatial proximity of xenobiotic had a substantial effect on the extent of degradation, with an additional effect of moisture content. Simultaneous addition of the compound and the degrader to the soil resulted in reduced mineralization dependence on mass transfer and microbial motility. Solution phase concentrations of the compound in the vicinity of the degraders were controlled by application method, however, overall fraction of solution phase substrate was not affected, suggesting that mineralization was limited by a localized lack of solution phase substrate. The results demonstrate a possible role of physical accessibility in environmental fate of xenobiotics.","abstract_has_math":false,"creators":["Johnson, Teresa Ann"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Natural Resrouces and Environmental Sciences","degree_department":null,"school":null,"contributors":["Sims, Gerald K."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T21:00:44Z","date_published":"2015-09-25T21:00:44Z","updated_at":"2026-07-22T22:26:20Z","subjects":["Environmental Sciences"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9953055"],"render_values":[{"text":"(MiAaPQ)AAI9953055","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/83144","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Sims, Gerald K."]},{"key":"dc:creator","label":"Author","values":["Johnson, Teresa Ann"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T21:00:44Z","10000-01-01","1999"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Natural Resrouces and Environmental Sciences"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Environmental Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/83144","(MiAaPQ)AAI9953055"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The influence of discontinuous water films on bioavailability of xenobiotics to soil microorganisms was examined in the third study. Comparisons were made between two scenarios for distributing the xenobiotic relative to an inoculated degrader under a range of soil moisture conditions. Spatial proximity of xenobiotic had a substantial effect on the extent of degradation, with an additional effect of moisture content. Simultaneous addition of the compound and the degrader to the soil resulted in reduced mineralization dependence on mass transfer and microbial motility. Solution phase concentrations of the compound in the vicinity of the degraders were controlled by application method, however, overall fraction of solution phase substrate was not affected, suggesting that mineralization was limited by a localized lack of solution phase substrate. The results demonstrate a possible role of physical accessibility in environmental fate of xenobiotics.","Made available in DSpace on 2015-09-25T21:00:44Z (GMT). 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Comparisons were made between two scenarios for distributing the xenobiotic relative to an inoculated degrader under a range of soil moisture conditions. Spatial proximity of xenobiotic had a substantial effect on the extent of degradation, with an additional effect of moisture content. Simultaneous addition of the compound and the degrader to the soil resulted in reduced mineralization dependence on mass transfer and microbial motility. Solution phase concentrations of the compound in the vicinity of the degraders were controlled by application method, however, overall fraction of solution phase substrate was not affected, suggesting that mineralization was limited by a localized lack of solution phase substrate. The results demonstrate a possible role of physical accessibility in environmental fate of xenobiotics.","Made available in DSpace on 2015-09-25T21:00:44Z (GMT). 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