{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/77426"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/77426","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"The Pressure Dependence of the Low Temperature Thermal Properties of an Amorphous Polymer","abstract":"The low-temperature behavior of glasses has been described as anomalous for its marked differences from crystalline behavior and as universal for its apparently weak dependence on chemical composition of the glass. For temperatures below 1 K the phenomemological Tunneling Model and the existence of phonons can account for the observed behavior, which is indicative of localized two-level excitations. For temperatures in the range 1 K-10 K there is no widely accepted model to explain the existence of an additional set of vibrational modes or the apparent sharp decrease in phonon mean free path. Some microscopic models for specific glasses imply that the 1 K-10 K regime and the sub-Kelvin regime are related. There is also a controversial theory that ascribes the behavior above 1 K to a universal phonon-fracton crossover in glasses. In order to gain some understanding of the nature of the two-level excitations and the excitations in the 1 K-10 K temperature range, the low-temperature thermal properties of Scotchcast-8 epoxy, an amorphous polymer, were used to probe glassy behavior as a function of pressure. The thermal measurements were performed over the range 0.3 K-10 K at pressures up to roughly 4 kbar. The low-temperature specific heat was observed to drop with pressure. The percent changes were rather uniform over the entire temperature range. For the thermal conductivity, the measurements reveal increased conductivity with pressure for temperatures above 1 K and indicate decreases with pressure for temperatures below 0.3K. From these measurements it is found that the energy density of two-level excitations decreases with pressure, while the coupling of these excitations to phonons increases. The measured changes in the 0.3K-1 K regime indicate that the density of two-level systems depends on the mass density $\\rho$ and the Debye temperature $\\Theta\\sb{\\rm D}$ as $\\rho$/$\\Theta\\sb{\\rm D}\\sp3$. The magnitude of the pressure-induced changes from 1 K-10 K suggests that the excess excitations and strong phonon scattering in this regime are most likely not related to structural length scales in the glass. Finally, the similar changes with pressure over the entire temperature range suggest that all the excitations, namely phonons, two-level systems, and the additional modes above 1 K, are related. These results are discussed with regard to the Tunneling Model, two microscopic models, and the controversial fraction theory.","abstract_html":"The low-temperature behavior of glasses has been described as anomalous for its marked differences from crystalline behavior and as universal for its apparently weak dependence on chemical composition of the glass. For temperatures below 1 K the phenomemological Tunneling Model and the existence of phonons can account for the observed behavior, which is indicative of localized two-level excitations. For temperatures in the range 1 K-10 K there is no widely accepted model to explain the existence of an additional set of vibrational modes or the apparent sharp decrease in phonon mean free path. Some microscopic models for specific glasses imply that the 1 K-10 K regime and the sub-Kelvin regime are related. There is also a controversial theory that ascribes the behavior above 1 K to a universal phonon-fracton crossover in glasses. In order to gain some understanding of the nature of the two-level excitations and the excitations in the 1 K-10 K temperature range, the low-temperature thermal properties of Scotchcast-8 epoxy, an amorphous polymer, were used to probe glassy behavior as a function of pressure. The thermal measurements were performed over the range 0.3 K-10 K at pressures up to roughly 4 kbar. The low-temperature specific heat was observed to drop with pressure. The percent changes were rather uniform over the entire temperature range. For the thermal conductivity, the measurements reveal increased conductivity with pressure for temperatures above 1 K and indicate decreases with pressure for temperatures below 0.3K. From these measurements it is found that the energy density of two-level excitations decreases with pressure, while the coupling of these excitations to phonons increases. The measured changes in the 0.3K-1 K regime indicate that the density of two-level systems depends on the mass density $\\rho$ and the Debye temperature $\\Theta\\sb{\\rm D}$ as $\\rho$/$\\Theta\\sb{\\rm D}\\sp3$. The magnitude of the pressure-induced changes from 1 K-10 K suggests that the excess excitations and strong phonon scattering in this regime are most likely not related to structural length scales in the glass. Finally, the similar changes with pressure over the entire temperature range suggest that all the excitations, namely phonons, two-level systems, and the additional modes above 1 K, are related. These results are discussed with regard to the Tunneling Model, two microscopic models, and the controversial fraction theory.","abstract_has_math":true,"creators":["Grace, Jeremy Matthew"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Physics","degree_department":null,"school":null,"contributors":["Anderson, A.C."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-05-13T15:42:04Z","date_published":"2015-05-13T15:42:04Z","updated_at":"2026-07-22T22:26:10Z","subjects":["Physics, Condensed Matter"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8908691"],"render_values":[{"text":"(UMI)AAI8908691","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/77426","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Anderson, A.C."]},{"key":"dc:creator","label":"Author","values":["Grace, Jeremy Matthew"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-05-13T15:42:04Z","10000-01-01","1988"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Physics"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Physics, Condensed Matter"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/77426","(UMI)AAI8908691"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The low-temperature behavior of glasses has been described as anomalous for its marked differences from crystalline behavior and as universal for its apparently weak dependence on chemical composition of the glass. For temperatures below 1 K the phenomemological Tunneling Model and the existence of phonons can account for the observed behavior, which is indicative of localized two-level excitations. For temperatures in the range 1 K-10 K there is no widely accepted model to explain the existence of an additional set of vibrational modes or the apparent sharp decrease in phonon mean free path. Some microscopic models for specific glasses imply that the 1 K-10 K regime and the sub-Kelvin regime are related. There is also a controversial theory that ascribes the behavior above 1 K to a universal phonon-fracton crossover in glasses. In order to gain some understanding of the nature of the two-level excitations and the excitations in the 1 K-10 K temperature range, the low-temperature thermal properties of Scotchcast-8 epoxy, an amorphous polymer, were used to probe glassy behavior as a function of pressure. The thermal measurements were performed over the range 0.3 K-10 K at pressures up to roughly 4 kbar. The low-temperature specific heat was observed to drop with pressure. The percent changes were rather uniform over the entire temperature range. For the thermal conductivity, the measurements reveal increased conductivity with pressure for temperatures above 1 K and indicate decreases with pressure for temperatures below 0.3K. From these measurements it is found that the energy density of two-level excitations decreases with pressure, while the coupling of these excitations to phonons increases. The measured changes in the 0.3K-1 K regime indicate that the density of two-level systems depends on the mass density $\\rho$ and the Debye temperature $\\Theta\\sb{\\rm D}$ as $\\rho$/$\\Theta\\sb{\\rm D}\\sp3$. The magnitude of the pressure-induced changes from 1 K-10 K suggests that the excess excitations and strong phonon scattering in this regime are most likely not related to structural length scales in the glass. Finally, the similar changes with pressure over the entire temperature range suggest that all the excitations, namely phonons, two-level systems, and the additional modes above 1 K, are related. These results are discussed with regard to the Tunneling Model, two microscopic models, and the controversial fraction theory.","Made available in DSpace on 2015-05-13T15:42:04Z (GMT). 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For temperatures below 1 K the phenomemological Tunneling Model and the existence of phonons can account for the observed behavior, which is indicative of localized two-level excitations. For temperatures in the range 1 K-10 K there is no widely accepted model to explain the existence of an additional set of vibrational modes or the apparent sharp decrease in phonon mean free path. Some microscopic models for specific glasses imply that the 1 K-10 K regime and the sub-Kelvin regime are related. There is also a controversial theory that ascribes the behavior above 1 K to a universal phonon-fracton crossover in glasses. In order to gain some understanding of the nature of the two-level excitations and the excitations in the 1 K-10 K temperature range, the low-temperature thermal properties of Scotchcast-8 epoxy, an amorphous polymer, were used to probe glassy behavior as a function of pressure. The thermal measurements were performed over the range 0.3 K-10 K at pressures up to roughly 4 kbar. The low-temperature specific heat was observed to drop with pressure. The percent changes were rather uniform over the entire temperature range. For the thermal conductivity, the measurements reveal increased conductivity with pressure for temperatures above 1 K and indicate decreases with pressure for temperatures below 0.3K. From these measurements it is found that the energy density of two-level excitations decreases with pressure, while the coupling of these excitations to phonons increases. The measured changes in the 0.3K-1 K regime indicate that the density of two-level systems depends on the mass density $\\rho$ and the Debye temperature $\\Theta\\sb{\\rm D}$ as $\\rho$/$\\Theta\\sb{\\rm D}\\sp3$. The magnitude of the pressure-induced changes from 1 K-10 K suggests that the excess excitations and strong phonon scattering in this regime are most likely not related to structural length scales in the glass. Finally, the similar changes with pressure over the entire temperature range suggest that all the excitations, namely phonons, two-level systems, and the additional modes above 1 K, are related. These results are discussed with regard to the Tunneling Model, two microscopic models, and the controversial fraction theory.","Made available in DSpace on 2015-05-13T15:42:04Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 8908691.PDF: 6088393 bytes, checksum: 49e970a4d1b988bc4c968880fcdf00c8 (MD5) Previous issue date: 1988","Embargo set by: Seth Robbins for item 78637 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","195 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1988."],"dc:identifier":["http://hdl.handle.net/2142/77426","(UMI)AAI8908691"],"dc:language":["eng"],"dc:subject":["Physics, Condensed Matter"],"dc:title":["The Pressure Dependence of the Low Temperature Thermal Properties of an Amorphous Polymer"],"dc:type":["text"],"thesis:degree_discipline":["Physics"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:10Z"}