Rism Methodology and Its Application to Orientational Correlations and to Excess Electrons in Liquids
A theory is presented for the orientational pair correlation factor, g(,2), of a molecular liquid in the interaction site picture. It is based on the so-called proper integral equation theory of molecular fluids and leads to a cluster series expansion for g(,2). A topological reduction which removes the bare Mayer f-bonds in favor of the appropriate pair correlation bonds is performed on this exact series.
University of Illinois - Urbana-Champaign
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University of Illinois at Urbana-Champaign