{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/71818"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/71818","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"The Kinetics and Thermodynamics of Oxygen in Nickel, Palladium, and Niobium-Vanadium Solid Solutions (Diffusion, Solubility, Electrochemistry)","abstract":"Solid-state electrochemical measurements using alternative experimental procedures were made with the double cell Ni + NiO(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni or Pd(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni + NiO to determine the kinetic and thermodynamic functions of oxygen in solid nickel and palladium. Non-steady state diffusion of oxygen in the specimen was caused by applying a preselected potential between the reference and specimen electrodes and was monitored by measuring time-dependent potentials and/or currents. The following results were obtained for the diffusivities and terminal solubilities of oxygen in nickel and palladium: D (Ni) = 4.9 x 10('-2) exp(-((164 kJ/mole)/RT)) cm('2)/sec (850-1400(DEGREES)C); C(,o)('s) (Ni) = 9.1 exp(-((56 kJ/mole)/RT)) at% (800-1000(DEGREES)C); D (Pd) = 1.03 x 10('-5) exp(-((98 kJ/mole)/RT)) cm('2)/sec (900-1150(DEGREES)C); C(,o)('s)(Pd) = 5.4 x 10('-2) exp(-((117 kJ/mole)/RT)) at% (900-1150(DEGREES)C).","abstract_html":"Solid-state electrochemical measurements using alternative experimental procedures were made with the double cell Ni + NiO(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni or Pd(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni + NiO to determine the kinetic and thermodynamic functions of oxygen in solid nickel and palladium. Non-steady state diffusion of oxygen in the specimen was caused by applying a preselected potential between the reference and specimen electrodes and was monitored by measuring time-dependent potentials and/or currents. The following results were obtained for the diffusivities and terminal solubilities of oxygen in nickel and palladium: D (Ni) = 4.9 x 10('-2) exp(-((164 kJ/mole)/RT)) cm('2)/sec (850-1400(DEGREES)C); C(,o)('s) (Ni) = 9.1 exp(-((56 kJ/mole)/RT)) at% (800-1000(DEGREES)C); D (Pd) = 1.03 x 10('-5) exp(-((98 kJ/mole)/RT)) cm('2)/sec (900-1150(DEGREES)C); C(,o)('s)(Pd) = 5.4 x 10('-2) exp(-((117 kJ/mole)/RT)) at% (900-1150(DEGREES)C).","abstract_has_math":false,"creators":["Park, Jong-Wan"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Metallurgical Engineering","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-16T20:52:00Z","date_published":"2014-12-16T20:52:00Z","updated_at":"2026-07-22T22:26:05Z","subjects":["Engineering, Metallurgy"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8511656"],"render_values":[{"text":"(UMI)AAI8511656","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/71818","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Park, Jong-Wan"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-16T20:52:00Z","10000-01-01","1985"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Metallurgical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Engineering, Metallurgy"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/71818","(UMI)AAI8511656"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Solid-state electrochemical measurements using alternative experimental procedures were made with the double cell Ni + NiO(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni or Pd(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni + NiO to determine the kinetic and thermodynamic functions of oxygen in solid nickel and palladium. Non-steady state diffusion of oxygen in the specimen was caused by applying a preselected potential between the reference and specimen electrodes and was monitored by measuring time-dependent potentials and/or currents. The following results were obtained for the diffusivities and terminal solubilities of oxygen in nickel and palladium: D (Ni) = 4.9 x 10('-2) exp(-((164 kJ/mole)/RT)) cm('2)/sec (850-1400(DEGREES)C); C(,o)('s) (Ni) = 9.1 exp(-((56 kJ/mole)/RT)) at% (800-1000(DEGREES)C); D (Pd) = 1.03 x 10('-5) exp(-((98 kJ/mole)/RT)) cm('2)/sec (900-1150(DEGREES)C); C(,o)('s)(Pd) = 5.4 x 10('-2) exp(-((117 kJ/mole)/RT)) at% (900-1150(DEGREES)C).","Using single galvanic cells with zirconium sinks, the diffusivities of oxygen in Nb-V alloys were measured. Vanadium atoms trap oxygen more strongly in niobium than niobium atoms do in vanadium. The trap energy does not appear to depend on the substitutional concentration, up to 10 at%. An attempt was made to find correlations between the kinetic and thermodynamic behavior of oxygen in Nb-V alloys.","Made available in DSpace on 2014-12-16T20:52:00Z (GMT). No. of bitstreams: 1 8511656.pdf: 3657236 bytes, checksum: 7340bb6dad319fa7193ee55a9e9f0dfa (MD5) Previous issue date: 1985","Embargo set by: Seth Robbins for item 71984 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","138 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985."]},{"key":"dc:title","label":"Title","values":["The Kinetics and Thermodynamics of Oxygen in Nickel, Palladium, and Niobium-Vanadium Solid Solutions (Diffusion, Solubility, Electrochemistry)"]}]}],"canonical_facts":{"dc:creator":["Park, Jong-Wan"],"dc:date":["2014-12-16T20:52:00Z","10000-01-01","1985"],"dc:description":["Solid-state electrochemical measurements using alternative experimental procedures were made with the double cell Ni + NiO(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni or Pd(VBAR)ZrO(,2) + Y(,2)O(,3)(VBAR)Ni + NiO to determine the kinetic and thermodynamic functions of oxygen in solid nickel and palladium. Non-steady state diffusion of oxygen in the specimen was caused by applying a preselected potential between the reference and specimen electrodes and was monitored by measuring time-dependent potentials and/or currents. The following results were obtained for the diffusivities and terminal solubilities of oxygen in nickel and palladium: D (Ni) = 4.9 x 10('-2) exp(-((164 kJ/mole)/RT)) cm('2)/sec (850-1400(DEGREES)C); C(,o)('s) (Ni) = 9.1 exp(-((56 kJ/mole)/RT)) at% (800-1000(DEGREES)C); D (Pd) = 1.03 x 10('-5) exp(-((98 kJ/mole)/RT)) cm('2)/sec (900-1150(DEGREES)C); C(,o)('s)(Pd) = 5.4 x 10('-2) exp(-((117 kJ/mole)/RT)) at% (900-1150(DEGREES)C).","Using single galvanic cells with zirconium sinks, the diffusivities of oxygen in Nb-V alloys were measured. Vanadium atoms trap oxygen more strongly in niobium than niobium atoms do in vanadium. The trap energy does not appear to depend on the substitutional concentration, up to 10 at%. An attempt was made to find correlations between the kinetic and thermodynamic behavior of oxygen in Nb-V alloys.","Made available in DSpace on 2014-12-16T20:52:00Z (GMT). No. of bitstreams: 1 8511656.pdf: 3657236 bytes, checksum: 7340bb6dad319fa7193ee55a9e9f0dfa (MD5) Previous issue date: 1985","Embargo set by: Seth Robbins for item 71984 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","138 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985."],"dc:identifier":["http://hdl.handle.net/2142/71818","(UMI)AAI8511656"],"dc:subject":["Engineering, Metallurgy"],"dc:title":["The Kinetics and Thermodynamics of Oxygen in Nickel, Palladium, and Niobium-Vanadium Solid Solutions (Diffusion, Solubility, Electrochemistry)"],"dc:type":["text"],"thesis:degree_discipline":["Metallurgical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:05Z"}