{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/70394"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/70394","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Extension of Chromatographically - Derived Molecular Recognition Concepts to Stereoselective Reactions and Transformations","abstract":"Analogues of chiral stationary phases (CSPs) and analogues of enantiomeric analytes separable upon the CSPs were employed in the investigation of stereoselective reactions and transformations. N-(3,5-dinitrobenzoyl)phenylglycine and N-(3,5-dinitrobenzoyl)leucine were used to study the stereochemical course of the coupling of chiral acids and chiral amines.","abstract_html":"Analogues of chiral stationary phases (CSPs) and analogues of enantiomeric analytes separable upon the CSPs were employed in the investigation of stereoselective reactions and transformations. N-(3,5-dinitrobenzoyl)phenylglycine and N-(3,5-dinitrobenzoyl)leucine were used to study the stereochemical course of the coupling of chiral acids and chiral amines.","abstract_has_math":false,"creators":["Reno, Daniel Scott"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-15T23:19:09Z","date_published":"2014-12-15T23:19:09Z","updated_at":"2026-07-22T22:26:02Z","subjects":["Chemistry, Organic"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8803175"],"render_values":[{"text":"(UMI)AAI8803175","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/70394","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Reno, Daniel Scott"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-15T23:19:09Z","10000-01-01","1987"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Organic"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/70394","(UMI)AAI8803175"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Analogues of chiral stationary phases (CSPs) and analogues of enantiomeric analytes separable upon the CSPs were employed in the investigation of stereoselective reactions and transformations. N-(3,5-dinitrobenzoyl)phenylglycine and N-(3,5-dinitrobenzoyl)leucine were used to study the stereochemical course of the coupling of chiral acids and chiral amines.","A chiral stationary phase precursor, an ester of N-(2-naphthyl)alanine, was used as a chiral solvating agent in the first-order asymmetric transformation of thioesters derived from N-acyl amino acids. Both sets of studies provided results which suggest that the interactions which afford differentiation of enantiomers during chromatographic separation on CSPs may also influence the stereochemical course of coupling reactions and asymmetric transformations.","Made available in DSpace on 2014-12-15T23:19:09Z (GMT). No. of bitstreams: 1 8803175.pdf: 3413871 bytes, checksum: cd8f7d240121c974532fe84666e65508 (MD5) Previous issue date: 1987","Embargo set by: Seth Robbins for item 70560 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","109 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1987."]},{"key":"dc:title","label":"Title","values":["Extension of Chromatographically - Derived Molecular Recognition Concepts to Stereoselective Reactions and Transformations"]}]}],"canonical_facts":{"dc:creator":["Reno, Daniel Scott"],"dc:date":["2014-12-15T23:19:09Z","10000-01-01","1987"],"dc:description":["Analogues of chiral stationary phases (CSPs) and analogues of enantiomeric analytes separable upon the CSPs were employed in the investigation of stereoselective reactions and transformations. N-(3,5-dinitrobenzoyl)phenylglycine and N-(3,5-dinitrobenzoyl)leucine were used to study the stereochemical course of the coupling of chiral acids and chiral amines.","A chiral stationary phase precursor, an ester of N-(2-naphthyl)alanine, was used as a chiral solvating agent in the first-order asymmetric transformation of thioesters derived from N-acyl amino acids. Both sets of studies provided results which suggest that the interactions which afford differentiation of enantiomers during chromatographic separation on CSPs may also influence the stereochemical course of coupling reactions and asymmetric transformations.","Made available in DSpace on 2014-12-15T23:19:09Z (GMT). No. of bitstreams: 1 8803175.pdf: 3413871 bytes, checksum: cd8f7d240121c974532fe84666e65508 (MD5) Previous issue date: 1987","Embargo set by: Seth Robbins for item 70560 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","109 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1987."],"dc:identifier":["http://hdl.handle.net/2142/70394","(UMI)AAI8803175"],"dc:subject":["Chemistry, Organic"],"dc:title":["Extension of Chromatographically - Derived Molecular Recognition Concepts to Stereoselective Reactions and Transformations"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:02Z"}