{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/70303"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/70303","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Synthesis and Chemiluminescent Investigation of Malonyl Peroxides","abstract":"The three malonyl peroxides 4-methyl-4-phenyl-1,2-dioxolane-3,5-dione (3), 4-diphenylmethyl-4-methyl-1,2-dioxolane-3,5-dione (4), and 4-methyl-4-(1-propenyl)-1,2-dioxolane-3,5-dione (5) are prepared by the methanesulfonic acid catalyzed reaction of hydrogen peroxide with the parent malonic acids. Weak chemiluminescence is observed from all three peroxides when they are thermolyzed in the presence of an aromatic fluorescer. The CIEEL mechanism is applied to explain the production of the light in each system. The production of the light in each case is very inefficient. The attempted synthesis of a fourth malonyl peroxide, 4-methyl-4-(trans-(beta)-styryl)-1,2-dioxolane-3,5-dione (6), is also presented.","abstract_html":"The three malonyl peroxides 4-methyl-4-phenyl-1,2-dioxolane-3,5-dione (3), 4-diphenylmethyl-4-methyl-1,2-dioxolane-3,5-dione (4), and 4-methyl-4-(1-propenyl)-1,2-dioxolane-3,5-dione (5) are prepared by the methanesulfonic acid catalyzed reaction of hydrogen peroxide with the parent malonic acids. Weak chemiluminescence is observed from all three peroxides when they are thermolyzed in the presence of an aromatic fluorescer. The CIEEL mechanism is applied to explain the production of the light in each system. The production of the light in each case is very inefficient. The attempted synthesis of a fourth malonyl peroxide, 4-methyl-4-(trans-(beta)-styryl)-1,2-dioxolane-3,5-dione (6), is also presented.","abstract_has_math":false,"creators":["Porter, Judith Elizabeth"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-15T23:18:30Z","date_published":"2014-12-15T23:18:30Z","updated_at":"2026-07-22T22:26:02Z","subjects":["Chemistry, Organic"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8521861"],"render_values":[{"text":"(UMI)AAI8521861","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/70303","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Porter, Judith Elizabeth"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-15T23:18:30Z","10000-01-01","1985"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Organic"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/70303","(UMI)AAI8521861"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The three malonyl peroxides 4-methyl-4-phenyl-1,2-dioxolane-3,5-dione (3), 4-diphenylmethyl-4-methyl-1,2-dioxolane-3,5-dione (4), and 4-methyl-4-(1-propenyl)-1,2-dioxolane-3,5-dione (5) are prepared by the methanesulfonic acid catalyzed reaction of hydrogen peroxide with the parent malonic acids. Weak chemiluminescence is observed from all three peroxides when they are thermolyzed in the presence of an aromatic fluorescer. The CIEEL mechanism is applied to explain the production of the light in each system. The production of the light in each case is very inefficient. The attempted synthesis of a fourth malonyl peroxide, 4-methyl-4-(trans-(beta)-styryl)-1,2-dioxolane-3,5-dione (6), is also presented.","Made available in DSpace on 2014-12-15T23:18:30Z (GMT). No. of bitstreams: 1 8521861.pdf: 4186878 bytes, checksum: d3b19e9c5ef356ff9801458232f03f55 (MD5) Previous issue date: 1985","Embargo set by: Seth Robbins for item 70469 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","149 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985."]},{"key":"dc:title","label":"Title","values":["Synthesis and Chemiluminescent Investigation of Malonyl Peroxides"]}]}],"canonical_facts":{"dc:creator":["Porter, Judith Elizabeth"],"dc:date":["2014-12-15T23:18:30Z","10000-01-01","1985"],"dc:description":["The three malonyl peroxides 4-methyl-4-phenyl-1,2-dioxolane-3,5-dione (3), 4-diphenylmethyl-4-methyl-1,2-dioxolane-3,5-dione (4), and 4-methyl-4-(1-propenyl)-1,2-dioxolane-3,5-dione (5) are prepared by the methanesulfonic acid catalyzed reaction of hydrogen peroxide with the parent malonic acids. Weak chemiluminescence is observed from all three peroxides when they are thermolyzed in the presence of an aromatic fluorescer. The CIEEL mechanism is applied to explain the production of the light in each system. The production of the light in each case is very inefficient. The attempted synthesis of a fourth malonyl peroxide, 4-methyl-4-(trans-(beta)-styryl)-1,2-dioxolane-3,5-dione (6), is also presented.","Made available in DSpace on 2014-12-15T23:18:30Z (GMT). No. of bitstreams: 1 8521861.pdf: 4186878 bytes, checksum: d3b19e9c5ef356ff9801458232f03f55 (MD5) Previous issue date: 1985","Embargo set by: Seth Robbins for item 70469 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","149 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985."],"dc:identifier":["http://hdl.handle.net/2142/70303","(UMI)AAI8521861"],"dc:subject":["Chemistry, Organic"],"dc:title":["Synthesis and Chemiluminescent Investigation of Malonyl Peroxides"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:02Z"}