{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/70239"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/70239","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Photolysis of (Halomethyl)naphthalenes: An Investigation of the Heterolysis and Homolysis of Carbon-Halogen Bonds in (Arylmethyl)halides","abstract":"The photolysis of (halomethyl)naphthalenes in methanol and cyclohexane was examined by means of product and quantum yield studies, sensitization and quenching experiments, and the technique of transient absorption spectroscopy. Evidence is presented for three modes of heterolytic bond cleavage. The first originates from an excited singlet state, and may be direct or may involve an exciplex formed during sensitization. The second mode is through an exciplex of the (halomethyl)naphthalene and a triplet sensitizer. The third mode appears to be important only for (iodomethyl)naphthalene (19I) and involves formation of a complex between ground state 19I and atomic iodine which gives solvolysis product and diiodide radical ion on reaction with methanol. The triplet (halomethyl)naphthalenes are found to be unreactive. Carbon-halogen bond homolysis occurs apparently both from the direct photolysis and from sensitization via exciplex formation.","abstract_html":"The photolysis of (halomethyl)naphthalenes in methanol and cyclohexane was examined by means of product and quantum yield studies, sensitization and quenching experiments, and the technique of transient absorption spectroscopy. Evidence is presented for three modes of heterolytic bond cleavage. The first originates from an excited singlet state, and may be direct or may involve an exciplex formed during sensitization. The second mode is through an exciplex of the (halomethyl)naphthalene and a triplet sensitizer. The third mode appears to be important only for (iodomethyl)naphthalene (19I) and involves formation of a complex between ground state 19I and atomic iodine which gives solvolysis product and diiodide radical ion on reaction with methanol. The triplet (halomethyl)naphthalenes are found to be unreactive. Carbon-halogen bond homolysis occurs apparently both from the direct photolysis and from sensitization via exciplex formation.","abstract_has_math":false,"creators":["Slocum, Gregory Howard"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-15T23:18:04Z","date_published":"2014-12-15T23:18:04Z","updated_at":"2026-07-22T22:26:02Z","subjects":["Chemistry, Organic"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8409835"],"render_values":[{"text":"(UMI)AAI8409835","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/70239","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Slocum, Gregory Howard"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-15T23:18:04Z","10000-01-01","1984"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Organic"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/70239","(UMI)AAI8409835"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The photolysis of (halomethyl)naphthalenes in methanol and cyclohexane was examined by means of product and quantum yield studies, sensitization and quenching experiments, and the technique of transient absorption spectroscopy. Evidence is presented for three modes of heterolytic bond cleavage. The first originates from an excited singlet state, and may be direct or may involve an exciplex formed during sensitization. The second mode is through an exciplex of the (halomethyl)naphthalene and a triplet sensitizer. The third mode appears to be important only for (iodomethyl)naphthalene (19I) and involves formation of a complex between ground state 19I and atomic iodine which gives solvolysis product and diiodide radical ion on reaction with methanol. The triplet (halomethyl)naphthalenes are found to be unreactive. Carbon-halogen bond homolysis occurs apparently both from the direct photolysis and from sensitization via exciplex formation.","Made available in DSpace on 2014-12-15T23:18:04Z (GMT). No. of bitstreams: 1 8409835.pdf: 5308315 bytes, checksum: 86b09cce4c95191327613610780cb024 (MD5) Previous issue date: 1984","Embargo set by: Seth Robbins for item 70405 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","185 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1984."]},{"key":"dc:title","label":"Title","values":["Photolysis of (Halomethyl)naphthalenes: An Investigation of the Heterolysis and Homolysis of Carbon-Halogen Bonds in (Arylmethyl)halides"]}]}],"canonical_facts":{"dc:creator":["Slocum, Gregory Howard"],"dc:date":["2014-12-15T23:18:04Z","10000-01-01","1984"],"dc:description":["The photolysis of (halomethyl)naphthalenes in methanol and cyclohexane was examined by means of product and quantum yield studies, sensitization and quenching experiments, and the technique of transient absorption spectroscopy. Evidence is presented for three modes of heterolytic bond cleavage. The first originates from an excited singlet state, and may be direct or may involve an exciplex formed during sensitization. The second mode is through an exciplex of the (halomethyl)naphthalene and a triplet sensitizer. The third mode appears to be important only for (iodomethyl)naphthalene (19I) and involves formation of a complex between ground state 19I and atomic iodine which gives solvolysis product and diiodide radical ion on reaction with methanol. The triplet (halomethyl)naphthalenes are found to be unreactive. Carbon-halogen bond homolysis occurs apparently both from the direct photolysis and from sensitization via exciplex formation.","Made available in DSpace on 2014-12-15T23:18:04Z (GMT). No. of bitstreams: 1 8409835.pdf: 5308315 bytes, checksum: 86b09cce4c95191327613610780cb024 (MD5) Previous issue date: 1984","Embargo set by: Seth Robbins for item 70405 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","185 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1984."],"dc:identifier":["http://hdl.handle.net/2142/70239","(UMI)AAI8409835"],"dc:subject":["Chemistry, Organic"],"dc:title":["Photolysis of (Halomethyl)naphthalenes: An Investigation of the Heterolysis and Homolysis of Carbon-Halogen Bonds in (Arylmethyl)halides"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:02Z"}