{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/70169"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/70169","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Calorimetry and Structure-Reactivity Relationships in Hypervalent Compounds of Phosphorus and Sulfur","abstract":"Phosphoranoxide 1, or its conjugate acid (10), TBP 10-P-5 species, hydrolyze to diol phosphinate 11 in boiling ethanolic KOH (72 hours); this reaction is reversed by treating 11 with aqueous HCl. Under these conditions, hydrolysis of isoelectronic-isostructural 10-S-5 sulfurane oxide 2b gave n","abstract_html":"Phosphoranoxide 1, or its conjugate acid (10), TBP 10-P-5 species, hydrolyze to diol phosphinate 11 in boiling ethanolic KOH (72 hours); this reaction is reversed by treating 11 with aqueous HCl. Under these conditions, hydrolysis of isoelectronic-isostructural 10-S-5 sulfurane oxide 2b gave n","abstract_has_math":false,"creators":["Ross, Michael Reiff"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-15T23:17:28Z","date_published":"2014-12-15T23:17:28Z","updated_at":"2026-07-22T22:26:02Z","subjects":["Chemistry, Organic"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8203571"],"render_values":[{"text":"(UMI)AAI8203571","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/70169","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Ross, Michael Reiff"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-15T23:17:28Z","10000-01-01","1981"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Organic"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/70169","(UMI)AAI8203571"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Phosphoranoxide 1, or its conjugate acid (10), TBP 10-P-5 species, hydrolyze to diol phosphinate 11 in boiling ethanolic KOH (72 hours); this reaction is reversed by treating 11 with aqueous HCl. Under these conditions, hydrolysis of isoelectronic-isostructural 10-S-5 sulfurane oxide 2b gave n","Made available in DSpace on 2014-12-15T23:17:28Z (GMT). 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