{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/67270"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/67270","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Azobenzene, Diphenylacetylene and Aromatic Nitrogen Heterocycles Coordinated to Early Transition Metal Metallocenes","abstract":"The structures of titanocene(azobenzene) (I), vanadocene(azobenzene) (II), vanadocene(diphenylacetylene) (III) and molybdenocene(diphenylacetylene) (IV) were determined using X-ray crystallography.","abstract_html":"The structures of titanocene(azobenzene) (I), vanadocene(azobenzene) (II), vanadocene(diphenylacetylene) (III) and molybdenocene(diphenylacetylene) (IV) were determined using X-ray crystallography.","abstract_has_math":false,"creators":["Willis, William Steven"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-12-13T20:11:15Z","date_published":"2014-12-13T20:11:15Z","updated_at":"2026-07-22T22:25:57Z","subjects":["Chemistry, Inorganic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(UMI)AAI8114501"],"render_values":[{"text":"(UMI)AAI8114501","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/67270","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Willis, William Steven"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-12-13T20:11:15Z","10000-01-01","1981"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Inorganic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/67270","(UMI)AAI8114501"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The structures of titanocene(azobenzene) (I), vanadocene(azobenzene) (II), vanadocene(diphenylacetylene) (III) and molybdenocene(diphenylacetylene) (IV) were determined using X-ray crystallography.","Compound (I) crystallizes in space group P2(,(VBAR))2(,(VBAR))2(,(VBAR)) (a = 11.430(31), b","Made available in DSpace on 2014-12-13T20:11:15Z (GMT). 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