Mechanisms of Chemiluminescence
type: CreativeWork
description: 3-Acetyl-4,4-dimethyl-1,2-dioxetane (1) was prepared by the base-catalyzed rearrangement of 4-bromo-3-hydroxy-3,5,5-trimethyl-1,2-dioxolane. Thermal decomposition of this dissymmetric dioxetane to acetone and methylglyoxal proceeds with an activation energy of 26.0 (+OR-) 1 kcal/mol and a log A of 14.2. The enthalpy of activation and entropy of activation were determined to be 25.5 (+OR-) 1.0 kcal/mol and 4.0 (+OR-) 2 eu, respectively. The total yield of excited states produced in the thermal decomposition was determined to be (17 (+OR-) 3) %. Both excited state acetone and excited state methylglyoxal were detected. The excited state multiplicities and yields are: acetone triplet (0.45 (+OR-) 0.20)%, methylglyoxal singlet (1.6 (+OR-) 0.5)%, and methylglyoxal triplet (15 (+OR-) 3)%. No singlet excited state acetone was detected. It is suggested that the observed excited state yields and the low triplet to singlet excited state methylglyoxal ratio can best be rationalized in terms of the energetics of a stepwise bi-radical decomposition of the dioxetane.
abstract: 3-Acetyl-4,4-dimethyl-1,2-dioxetane (1) was prepared by the base-catalyzed rearrangement of 4-bromo-3-hydroxy-3,5,5-trimethyl-1,2-dioxolane. Thermal decomposition of this dissymmetric dioxetane to acetone and methylglyoxal proceeds with an activation energy of 26.0 (+OR-) 1 kcal/mol and a log A of 14.2. The enthalpy of activation and entropy of activation were determined to be 25.5 (+OR-) 1.0 kcal/mol and 4.0 (+OR-) 2 eu, respectively. The total yield of excited states produced in the thermal decomposition was determined to be (17 (+OR-) 3) %. Both excited state acetone and excited state methylglyoxal were detected. The excited state multiplicities and yields are: acetone triplet (0.45 (+OR-) 0.20)%, methylglyoxal singlet (1.6 (+OR-) 0.5)%, and methylglyoxal triplet (15 (+OR-) 3)%. No singlet excited state acetone was detected. It is suggested that the observed excited state yields and the low triplet to singlet excited state methylglyoxal ratio can best be rationalized in terms of the energetics of a stepwise bi-radical decomposition of the dioxetane.
author: Horn, Keith Alan
language: eng
keywords: Chemistry, Organic
date published: 2014-12-13T20:10:53Z
date modified: 2026-07-22T22:25:57Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/67221