{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/129167"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/129167","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Automating electrochemical characterization for studies in energy storage and conversion","abstract":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-10-19 without embargo terms","abstract_html":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-10-19 without embargo terms","abstract_has_math":false,"creators":["Pence, Michael A."],"institution":"University of Illinois Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Rodríguez-López, Joaquín","Kenis, Paul J.A.","Han, Hee-Sun","Jackson, Nicholas E."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2025,"date_issued":"2025-02-13","date_published":"2025-02-13","updated_at":"2026-07-22T22:25:04Z","subjects":["Electrochemistry","Automation"],"languages":["en","eng"],"rights":["Copyright 2025 Michael Pence"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/129167","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Rodríguez-López, Joaquín","Kenis, Paul J.A.","Han, Hee-Sun","Jackson, Nicholas E."]},{"key":"dc:creator","label":"Author","values":["Pence, Michael A."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2025-02-13","2025-05"]},{"key":"dc:type","label":"Dc Type","values":["text","Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Electrochemistry","Automation"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2025 Michael Pence"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/129167"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-10-19 without embargo terms","The student, Michael Pence, accepted the attached license on 2025-02-06 at 21:06.","The student, Michael Pence, submitted this Dissertation for approval on 2025-02-06 at 21:07.","This Dissertation was approved for publication on 2025-02-13 at 15:42.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21636 on 2025-10-19 at 18:08:43","The climate crisis requires a dramatic change in the way we generate and utilize energy, shifting from fossil fuels to green and sustainable technologies. Technologies based on electrochemical principles are at the center of this energy revolution, but the discovery and optimization of emerging electrochemical systems require rapid progress to match the urgency of mounting societal pressures. To this end, laboratory automation in electrochemistry aims to accelerate discovery by increasing experimental throughput through continuous and passive experimentation. This thesis aims to develop a comprehensive toolbox for automating electrochemistry, enabling accelerated experimental throughput for electrochemical characterization of emerging technologies in energy storage (redox-flow batteries) and energy conversion (molecular catalysis). Chapter 1 reviews current progress in the field of automated electrochemistry with a focus the hardware design and construction of automated platforms. Chapter 2 presents the development of multiplexed and microfabricated electrode arrays as an enabling tool for automated measurement of redox-flow battery decomposition. Chapter 3 couples the microfabricated array strategy from Chapter 2 with an automated solution handling robot, the Electrolab, to study ionic strength-dependent dynamics of polyelectrolytes. Moving beyond energy storage, Chapter 4 demonstrates a streamlined automated electrochemistry platform, eLab, that integrates pH measurement into the experimental workflow to enable the study of the pH-dependent kinetics of electrocatalyzed alcohol oxidation. Chapter 5 incorporates the eLab platform with Bayesian optimization to autonomously identify experimental parameters that yield kinetically informative current-potential curves, finding application in molecular electrocatalysis. Finally, Chapter 6 provides an outlook on the future of automated electrochemistry, highlighting exciting avenues for further research."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Automating electrochemical characterization for studies in energy storage and conversion"]}]}],"canonical_facts":{"dc:contributor":["Rodríguez-López, Joaquín","Kenis, Paul J.A.","Han, Hee-Sun","Jackson, Nicholas E."],"dc:creator":["Pence, Michael A."],"dc:date":["2025-02-13","2025-05"],"dc:description":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-10-19 without embargo terms","The student, Michael Pence, accepted the attached license on 2025-02-06 at 21:06.","The student, Michael Pence, submitted this Dissertation for approval on 2025-02-06 at 21:07.","This Dissertation was approved for publication on 2025-02-13 at 15:42.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21636 on 2025-10-19 at 18:08:43","The climate crisis requires a dramatic change in the way we generate and utilize energy, shifting from fossil fuels to green and sustainable technologies. Technologies based on electrochemical principles are at the center of this energy revolution, but the discovery and optimization of emerging electrochemical systems require rapid progress to match the urgency of mounting societal pressures. 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Moving beyond energy storage, Chapter 4 demonstrates a streamlined automated electrochemistry platform, eLab, that integrates pH measurement into the experimental workflow to enable the study of the pH-dependent kinetics of electrocatalyzed alcohol oxidation. Chapter 5 incorporates the eLab platform with Bayesian optimization to autonomously identify experimental parameters that yield kinetically informative current-potential curves, finding application in molecular electrocatalysis. Finally, Chapter 6 provides an outlook on the future of automated electrochemistry, highlighting exciting avenues for further research."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/129167"],"dc:language":["en","eng"],"dc:rights":["Copyright 2025 Michael Pence"],"dc:subject":["Electrochemistry","Automation"],"dc:title":["Automating electrochemical characterization for studies in energy storage and conversion"],"dc:type":["text","Thesis"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois Urbana-Champaign"]},"updated_at":"2026-07-22T22:25:04Z"}