{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/127470"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/127470","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Size and composition control of specialty nanocatalysts for sustainability: Fuel cell cathode material and production of sustainable aviation fuel","abstract":"Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-12-01","abstract_html":"Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-12-01","abstract_has_math":false,"creators":["Yu, Siying"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemical Engineering","degree_department":null,"school":null,"contributors":["Rao, Christopher V.","Su, Xiao","Yang, Hong","Zhang, Yuanhui","Peters, Baron G."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2024,"date_issued":"2024-11-26","date_published":"2024-11-26","updated_at":"2026-07-22T22:25:04Z","subjects":["Platinum-based Intermetallic Nanoparticles","Molybdenum Carbide Nanocatalysts","Sustainable Aviation Fuel"],"languages":["en","eng"],"rights":["Copyright 2024 Siying Yu"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/127470","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Rao, Christopher V.","Su, Xiao","Yang, Hong","Zhang, Yuanhui","Peters, Baron G."]},{"key":"dc:creator","label":"Author","values":["Yu, Siying"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2024-11-26","2024-12"]},{"key":"dc:type","label":"Dc Type","values":["text","Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Platinum-based Intermetallic Nanoparticles","Molybdenum Carbide Nanocatalysts","Sustainable Aviation Fuel"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2024 Siying Yu"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/127470"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-12-01","The student, Siying Yu, accepted the attached license on 2024-11-25 at 19:56.","The student, Siying Yu, submitted this Dissertation for approval on 2024-11-25 at 20:15.","This Dissertation was approved for publication on 2024-11-26 at 11:45.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21391 on 2025-03-28 at 14:55:13","Sustainable energy technologies are required to reduce greenhouse gas emissions and fulfill growing energy demands. The transition from conventional fossil fuels to renewable-generated energy requires scientific and technical breakthroughs that deliver favorable energy- and cost-efficiency. Noble metal-based catalysts applied to sustainable energy technologies are catalytically reactive but less economical than low-platinum group metal (PGM) and PGM-free nanomaterials. This thesis focuses on (1) platinum-based binary intermetallic nanoparticles for proton exchange membrane fuel cells (PEMFCs) and (2) molybdenum carbide nanocatalysts for the production of sustainable aviation fuel (SAF). Platinum-cobalt (PtCo) intermetallic nanoparticles have been proven to be good substitutions to reduce the amount of precious metal required in PEMFCs. The near-term challenge is to develop a facile and scalable production of PtCo nanoparticles with controlled size and composition to satisfy the needs of heavy-duty PEMFCs. Similarly, molybdenum carbide nanoparticles are reported as promising hydrodeoxygenation (HDO) catalysts to replace platinum and palladium in producing SAF. However, their reported performance is mainly based on pure-phase model compounds such as oleic acid instead of real biofuels. An in-depth investigation of the effects of structural and compositional factors of molybdenum carbides on catalytic properties in real biocrude oils is required. Thus, this thesis is divided into two parts: the first part reports facile synthetic approaches of dense, sub-5 nm Pt-based intermetallic nanoparticles using a dual-ligand metal organic framework as atomically dispersed precursors. Sacrificial metal (zinc) in the precursors were found to contribute to the size control of Pt-based nanoparticles by creating vacancies and facilitating atomic diffusion. The second part of the thesis showcases the excellent HDO activity (~100% deoxygenation efficiency) of supported molybdenum carbide nanocatalysts in food-waste-derived biocrude oils, which were further converted to SAF candidate via distillation. Effects of several key structural and compositional factors, i.e., particle size, Fe loading, and surface oxidation on HDO activity, were also investigated."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Size and composition control of specialty nanocatalysts for sustainability: Fuel cell cathode material and production of sustainable aviation fuel"]}]}],"canonical_facts":{"dc:contributor":["Rao, Christopher V.","Su, Xiao","Yang, Hong","Zhang, Yuanhui","Peters, Baron G."],"dc:creator":["Yu, Siying"],"dc:date":["2024-11-26","2024-12"],"dc:description":["Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-12-01","The student, Siying Yu, accepted the attached license on 2024-11-25 at 19:56.","The student, Siying Yu, submitted this Dissertation for approval on 2024-11-25 at 20:15.","This Dissertation was approved for publication on 2024-11-26 at 11:45.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21391 on 2025-03-28 at 14:55:13","Sustainable energy technologies are required to reduce greenhouse gas emissions and fulfill growing energy demands. The transition from conventional fossil fuels to renewable-generated energy requires scientific and technical breakthroughs that deliver favorable energy- and cost-efficiency. Noble metal-based catalysts applied to sustainable energy technologies are catalytically reactive but less economical than low-platinum group metal (PGM) and PGM-free nanomaterials. This thesis focuses on (1) platinum-based binary intermetallic nanoparticles for proton exchange membrane fuel cells (PEMFCs) and (2) molybdenum carbide nanocatalysts for the production of sustainable aviation fuel (SAF). Platinum-cobalt (PtCo) intermetallic nanoparticles have been proven to be good substitutions to reduce the amount of precious metal required in PEMFCs. The near-term challenge is to develop a facile and scalable production of PtCo nanoparticles with controlled size and composition to satisfy the needs of heavy-duty PEMFCs. Similarly, molybdenum carbide nanoparticles are reported as promising hydrodeoxygenation (HDO) catalysts to replace platinum and palladium in producing SAF. However, their reported performance is mainly based on pure-phase model compounds such as oleic acid instead of real biofuels. An in-depth investigation of the effects of structural and compositional factors of molybdenum carbides on catalytic properties in real biocrude oils is required. Thus, this thesis is divided into two parts: the first part reports facile synthetic approaches of dense, sub-5 nm Pt-based intermetallic nanoparticles using a dual-ligand metal organic framework as atomically dispersed precursors. Sacrificial metal (zinc) in the precursors were found to contribute to the size control of Pt-based nanoparticles by creating vacancies and facilitating atomic diffusion. The second part of the thesis showcases the excellent HDO activity (~100% deoxygenation efficiency) of supported molybdenum carbide nanocatalysts in food-waste-derived biocrude oils, which were further converted to SAF candidate via distillation. Effects of several key structural and compositional factors, i.e., particle size, Fe loading, and surface oxidation on HDO activity, were also investigated."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/127470"],"dc:language":["en","eng"],"dc:rights":["Copyright 2024 Siying Yu"],"dc:subject":["Platinum-based Intermetallic Nanoparticles","Molybdenum Carbide Nanocatalysts","Sustainable Aviation Fuel"],"dc:title":["Size and composition control of specialty nanocatalysts for sustainability: Fuel cell cathode material and production of sustainable aviation fuel"],"dc:type":["text","Thesis"],"thesis:degree_discipline":["Chemical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:25:04Z"}