{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/127167"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/127167","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Expanding the chemical tunability and precision of bottlebrush polymer synthesis","abstract":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-03-28 without embargo terms","abstract_html":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-03-28 without embargo terms","abstract_has_math":false,"creators":["Kamble, Yash Laxman"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemical Engineering","degree_department":null,"school":null,"contributors":["Guironnet, Damien","Diao, Ying","Sing, Charles E","Wang, Hua"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2024,"date_issued":"2024-11-01","date_published":"2024-11-01","updated_at":"2026-07-22T22:25:03Z","subjects":["Polymers","Bottlebrush Polymers","Ring Opening Metathesis Polymerization","Group Transfer Polymerization","Structural Color"],"languages":["en","eng"],"rights":["Copyright 2024 Yash Kamble"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/127167","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Guironnet, Damien","Diao, Ying","Sing, Charles E","Wang, Hua"]},{"key":"dc:creator","label":"Author","values":["Kamble, Yash Laxman"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2024-11-01","2024-12"]},{"key":"dc:type","label":"Dc Type","values":["text","Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Polymers","Bottlebrush Polymers","Ring Opening Metathesis Polymerization","Group Transfer Polymerization","Structural Color"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2024 Yash Kamble"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/127167"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-03-28 without embargo terms","The student, Yash Kamble, accepted the attached license on 2024-10-25 at 09:49.","The student, Yash Kamble, submitted this Dissertation for approval on 2024-10-25 at 09:58.","This Dissertation was approved for publication on 2024-11-01 at 15:34.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21274 on 2025-03-28 at 14:25:15","The pursuit of engineering macroscopic properties in polymeric materials has heightened the need to precisely control polymer microstructure, including architecture, size, and chemistry. Advances in synthetic methodologies and characterization techniques have facilitated the creation of well-defined functional polymers, establishing efficient structure-function relationships. However, challenges persist in independently controlling design parameters to elucidate molecular relationships between microstructure and macroscopic properties. To address this limitation, my research focused on developing synthetic methodologies for tuning the architecture, size, and composition of densely grafted polymers, known as bottlebrush polymers. This thesis outlines several methodologies for enhancing chemical tunability through side chain chemistry, bottlebrush polymer size, and architecture. These methods enable precise control over the shape (e.g., varying brush lengths along the backbone), chemistry (e.g., diverse brush chemistries and end-group functionalities), and size (e.g., brush and backbone lengths) of bottlebrush polymers, accompanied by rigorous characterization. The methodologies detailed in this thesis enhance the chemical tunability of bottlebrush polymers, providing a unique platform for correlating polymer microstructure with macroscopic properties. This approach aims to establish effective design rules and structure-function relationships for targeted applications in polymeric materials."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Expanding the chemical tunability and precision of bottlebrush polymer synthesis"]}]}],"canonical_facts":{"dc:contributor":["Guironnet, Damien","Diao, Ying","Sing, Charles E","Wang, Hua"],"dc:creator":["Kamble, Yash Laxman"],"dc:date":["2024-11-01","2024-12"],"dc:description":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-03-28 without embargo terms","The student, Yash Kamble, accepted the attached license on 2024-10-25 at 09:49.","The student, Yash Kamble, submitted this Dissertation for approval on 2024-10-25 at 09:58.","This Dissertation was approved for publication on 2024-11-01 at 15:34.","DSpace SAF Submission Ingestion Package generated from Vireo submission #21274 on 2025-03-28 at 14:25:15","The pursuit of engineering macroscopic properties in polymeric materials has heightened the need to precisely control polymer microstructure, including architecture, size, and chemistry. Advances in synthetic methodologies and characterization techniques have facilitated the creation of well-defined functional polymers, establishing efficient structure-function relationships. However, challenges persist in independently controlling design parameters to elucidate molecular relationships between microstructure and macroscopic properties. To address this limitation, my research focused on developing synthetic methodologies for tuning the architecture, size, and composition of densely grafted polymers, known as bottlebrush polymers. This thesis outlines several methodologies for enhancing chemical tunability through side chain chemistry, bottlebrush polymer size, and architecture. These methods enable precise control over the shape (e.g., varying brush lengths along the backbone), chemistry (e.g., diverse brush chemistries and end-group functionalities), and size (e.g., brush and backbone lengths) of bottlebrush polymers, accompanied by rigorous characterization. The methodologies detailed in this thesis enhance the chemical tunability of bottlebrush polymers, providing a unique platform for correlating polymer microstructure with macroscopic properties. This approach aims to establish effective design rules and structure-function relationships for targeted applications in polymeric materials."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/127167"],"dc:language":["en","eng"],"dc:rights":["Copyright 2024 Yash Kamble"],"dc:subject":["Polymers","Bottlebrush Polymers","Ring Opening Metathesis Polymerization","Group Transfer Polymerization","Structural Color"],"dc:title":["Expanding the chemical tunability and precision of bottlebrush polymer synthesis"],"dc:type":["text","Thesis"],"thesis:degree_discipline":["Chemical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:25:03Z"}